The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
Sulphate of soda 9
Nitrate of lead 20·75
------
29·75
and the quantities of the new salts formed will be
Sulphate of lead 19
Nitrate of soda 10·75
-----
29·75
We see that the absolute weights of the two sets of salts are the
same: all that has happened is, that both the acids and both the bases
have exchanged situations. Now if, instead of mixing these two salts
together in the preceding proportions, we employ
Sulphate of soda 9
Nitrate of lead 25·75
That is to say, if we employ 5 parts of nitrate of lead more than
is sufficient for the purpose; we shall have exactly the same
decompositions as before; but the 5 of excess of nitrate of lead will
remain in solution, mixed with the nitrate of soda. There will be
precipitated as before,
Sulphate of lead 19
and there will remain in solution a mixture of
Nitrate of soda 10·75
Nitrate of lead 5
The phenomena are precisely the same as before; the additional 5 of
nitrate of lead have occasioned no alteration; the decomposition has
gone on just as if they had not been present.
Now the phenomena which drew the particular attention of Wenzel is,
that if the salts were neutral before being mixed, the neutrality
was not affected by the decomposition which took place on their
mixture.[7] A salt is said to be neutral when it neither possesses the
characters of an acid or an alkali. Acids _redden_ vegetable _blues_,
while alkalies render them _green_. A neutral salt produces no effect
whatever upon vegetable blues. This observation of Wenzel is very
important: it is obvious that the salts, after their decomposition,
could not have remained neutral unless the elements of the two salts
had been such that the bases in each just saturated the acids in either
of the salts.
[7] This observation is not without exception. It does not hold when
one of the salts is a phosphate or an arseniate, and this is the cause
of the difficulty attending the analysis of these genera of salts.
The constituents of the two salts are as follows:
{ 5 sulphuric acid
9 sulphate of soda { 4 soda,
{ 6·75 nitric acid
20·75 nitrate of lead {14 oxide of lead.
Now it is clear, that unless 5 sulphuric acid were just saturated by
4 soda and by 14 oxide of lead; and 6·75 of nitric acid by the same 4
soda and 14 oxide of lead, the salts, after their decomposition, could
not have preserved their neutrality. Had 4 soda required only 5·75 of
nitric acid, or had 14 oxide of lead required only 4 sulphuric acid, to
saturate them, the liquid, after decomposition, would have contained
an excess of acid. As no such excess exists, it is clear that in
saturating an acid, 4 soda goes exactly as far as 14 oxide of lead; and
that, in saturating a base, 5 sulphuric acid goes just as far as 6·75
nitric acid.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account