The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
Most of the specimens of manganese ore which Scheele examined,
contained more or less barytes, as has since been determined, in
combination with the oxide. He separated this barytes, and determined
its peculiar properties. It dissolved in nitric and muriatic acids,
and formed salts capable of crystallizing, and permanent in the air.
Neither potash, soda, nor lime, nor any _base_ whatever, was capable of
precipitating it from these acids. But the alkaline carbonates threw it
down in the state of a white powder, which dissolved with effervescence
in acids. Sulphuric acid and all the sulphates threw it down in the
state of a white powder, which was insoluble in water and in acids.
This sulphate cannot be decomposed by any acid or base whatever. The
only practicable mode of proceeding is to convert the sulphuric acid
into sulphur, by heating the salt with charcoal powder, along with a
sufficient quantity of potash, to bring the whole into fusion. The
fused mass, edulcorated, is soluble in nitric or muriatic acid, and
thus may be freed from charcoal, and the barytes obtained in a state
of purity. Scheele detected barytes, also, in the potash made from
trees or other smaller vegetables; but at that time he was unacquainted
with _sulphate of barytes_, which is so common in various parts of the
earth, especially in lead-mines.
To point out all the new facts contained in this admirable essay,
it would be necessary to transcribe the whole of it. He shows the
remarkable analogy between manganese and metallic oxides. Bergman, in
an appendix affixed to Scheele's paper, states his reasons for being
satisfied that it is really a metallic oxide. Some years afterwards,
Assessor Gahn succeeded in reducing it to the metallic state, and thus
dissipating all remaining doubts on the subject.
4. In 1775 he gave a new method of obtaining benzoic acid from benzoin.
His method was, to digest the benzoin with pounded chalk and water,
till the whole of the acid had combined with lime, and dissolved in the
water. It is requisite to take care to prevent the benzoin from running
into clots. The liquid thus containing benzoate of lime in solution is
filtered, and muriatic acid added in sufficient quantity to saturate
the lime. The benzoic acid is separated in white flocks, which may be
easily collected and washed. This method, though sufficiently easy, is
not followed by practical chemists, at least in this country. The acid
when procured by precipitation is not so beautiful as what is procured
by sublimation; nor is the process so cheap or so rapid. For these
reasons, Scheele's process has not come into general use.
Public-domain text, read in full here on John Shaqi.
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