The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
9. In the year 1777 was published the Experiments of Scheele on Air
and Fire, with an introduction, by way of preface, from Bergman, who
seems to have superintended the publication. This work is undoubtedly
the most extraordinary production that Scheele has left us; and is
really wonderful, if we consider the circumstances under which it was
produced. Scheele ascertained that common air is a mixture of two
distinct elastic fluids, one of which alone is capable of supporting
combustion, and which, therefore, he calls _empyreal air_; the
other, being neither capable of maintaining combustion, nor of being
breathed, he called _foul air_. These are the _oxygen_ and _azote_
of modern chemists. Oxygen he showed to be heavier than common air;
bodies burnt in it with much greater splendour than in common air.
Azote he found lighter than common air; bodies would not burn in it at
all. He showed that metallic _calces_, or metallic _oxides_, as they
are now called, contain oxygen as a constituent, and that when they
are reduced to the metallic state, oxygen gas is disengaged. In his
experiments on fulminating gold he shows, that during the fulmination
a quantity of azotic gas is disengaged; and he deduces from a great
many curious facts, which are stated at length, that ammonia is a
compound of _azote_ and _hydrogen_. His apparatus was not nice enough
to enable him to determine the proportions of the various ingredients
of the bodies which he analyzed: accordingly that is seldom attempted;
and when it is, as was the case with common air, the results are very
unsatisfactory. He deduces from his experiments, that the volume of
oxygen gas, in common air, is between a third and a fourth: we now know
that it is exactly a fifth.
In this book, also, we have the first account of sulphuretted
hydrogen gas, and of its properties. He gives it the name of stinking
sulphureous air.
Public-domain text, read in full here on John Shaqi.
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