The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
The observations and new views respecting heat and light in this
work are so numerous, that I am obliged to omit them: nor do I think
it necessary to advert to his theory, which, when his book was
published, was exceedingly plausible, and undoubtedly constituted
a great step towards the improvements which soon after followed.
His own experiments, had he attended a little more closely to the
_weights_, and the alterations of them, would have been sufficient
to have overturned the whole doctrine of phlogiston. Upon the whole
it may be said, with confidence, that there is no chemical book in
existence which contains a greater number of new and important facts
than this work of Scheele, at the time it was published. Yet most of
his discoveries were made, also, by others. Priestley and Lavoisier,
from the superiority of their situations, and their greater means of
making their labours speedily known to the public, deprived him of
much of that reputation to which, in common circumstances, he would
have been entitled. Priestley has been blamed for the rapidity of his
publications, and the crude manner in which he ushered his discoveries
to the world. But had he kept them by him till he had brought them to
a sufficient degree of maturity, it is obvious that he would have been
anticipated in the most important of them by Scheele.
10. In the Memoirs of the Stockholm Academy, for 1779, there is a
short but curious paper of Scheele, giving an account of some results
which he had obtained. If a plate of iron be moistened by a solution
of common salt, or of sulphate of soda, and left for some weeks in a
moist cellar, an efflorescence of carbonate of soda covers the surface
of the plate. The same decomposition of common salt and evolution of
soda takes place when unslacked quicklime is moistened with a solution
of common salt, and left in a similar situation. These experiments led
afterwards to various methods of decomposing common salt, and obtaining
from it carbonate of soda. The phenomena themselves are still wrapped
up in considerable obscurity. Berthollet attempted an explanation
afterwards in his Chemical Statics; but founded on principles not
easily admissible.
11. During the same year, his experiments on _plumbago_ were published.
This substance had been long employed for making black-lead pencils;
but nothing was known concerning its nature. Scheele, with his usual
perseverance, tried the effect of all the different reagents, and
showed that it consisted chiefly of _carbon_, but was mixed with a
certain quantity of iron. It was concluded from these experiments,
that plumbago is a carburet of iron. But the quantity of iron differs
so enormously in different specimens, that this opinion cannot be
admitted. Sometimes the iron amounts only to one-half per cent., and
sometimes to thirty per cent. Plumbago, then, is carbon mixed with a
variable proportion of iron, or carburet of iron.
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