The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
16. In 1784 he pointed out a method by which _citric acid_ may be
obtained in a state of purity from lemon-juice. He likewise determined
its characters, and showed that it was entitled to rank as a peculiar
acid.
It was during the same year that he observed a white earthy matter,
which may be obtained by washing rhubarb, in fine powder, with a
sufficient quantity of water. This earthy matter he decomposed, and
ascertained that it was a neutral salt, composed of oxalic acid,
combined with lime. In a subsequent paper he showed, that the same
oxalate of lime exists in a great number of roots of various plants.
17. In 1786 he showed that apples contain a peculiar acid, the
properties of which he determined, and to which the name of _malic
acid_ has been given. In the same paper he examined all the common acid
fruits of this country--gooseberries, currants, cherries, bilberries,
&c., and determined the peculiar acids which they contain. Some owe
their acidity to malic acid, some to citric acid, and some to tartaric
acid; and not a few hold two, or even three, of these acids at the same
time.
The same year he showed that the syderum of Bergman was phosphuret of
iron, and the _acidum perlatum_ of Proust _biphosphate of soda_.
The only other publication of Scheele, during 1785, was a short
notice respecting a new mode of preparing _magnesia alba_. If
sulphate of magnesia and common salt, both in solution, be mixed in
the requisite proportions, a double decomposition takes place, and
there will be formed sulphate of soda and muriate of magnesia. The
greatest part of the former salt may be obtained out of the mixed ley
by crystallization, and then the magnesia alba may be thrown down,
from the muriate of magnesia, by means of an alkaline carbonate. The
advantage of this new process is, the procuring of a considerable
quantity of sulphate of soda in exchange for common salt, which is a
much cheaper substance.
18. The last paper which Scheele published appeared in the Memoirs
of the Stockholm Academy, for 1786: in it he gave an account of the
characters of gallic acid, and the method of obtaining that acid from
nutgalls.
Such is an imperfect sketch of the principal discoveries of Scheele.
I have left out of view his controversial papers, which have now lost
their interest; and a few others of minor importance, that this notice
might not be extended beyond its due length. It will be seen that
Scheele extended greatly the number of acids; indeed, he more than
doubled the number of these bodies known when he began his chemical
labours. The following acids were discovered by him; or, at least, it
was he that first accurately pointed out their characters:
Fluoric acid
Molybdic acid
Tungstic acid
Arsenic acid
Lactic acid
Gallic acid
Tartaric acid
Oxalic acid
Citric acid
Malic acid
Saclactic
Chlorine.
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