The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
12. In 1780 Scheele published his experiments on milk, and showed that
sour milk contains a peculiar acid, to which the name of _lactic_ acid
has been given.
He found that when sugar of milk is dissolved in nitric acid, and the
solution allowed to cool, small crystalline grains were deposited.
These grains have an acid taste, and combine with bases: they have
peculiar properties, and therefore constitute a particular acid, to
which the name of _saclactic_ was given. It is formed, also, when
gum is dissolved in nitric acid; on this account it has been called,
_mucic_ acid.
13. In 1781 his experiments on a heavy mineral called by the Swedes
_tungsten_, were published. This substance had been much noticed on
account of its great weight; but nothing was known respecting its
nature. Scheele, with his usual skill and perseverance, succeeded in
proving that it was a compound of lime and a peculiar acid, to which
the name of _tungstic acid_ was given. Tungsten was, therefore, a
tungstate of lime. Bergman, from its great weight, suspected that
tungstic acid was in reality the oxide of a metal, and this conjecture
was afterwards confirmed by the Elhuyarts, who extracted the same acid
from wolfram, and succeeded in reducing it to the metallic state.
14. In 1782 and 1783 appeared his experiments on _Prussian blue_, in
order to discover the nature of the colouring matter. These experiments
were exceedingly numerous, and display uncommon ingenuity and sagacity.
He succeeded in demonstrating that _prussic acid_, the name at that
time given to the colouring principle, was a compound of _carbon_ and
_azote_. He pointed out a process for obtaining prussic acid in a
separate state, and determined its properties. This paper threw at once
a ray of light on one of the obscurest parts of chemistry. If he did
not succeed in elucidating this difficult department completely, the
fault must not be ascribed to him, but to the state of chemistry when
his experiments were made; in fact, it would have been impossible to
have gone further, till the nature of the different elastic fluids at
that time under investigation had been thoroughly established. Perhaps
in 1783 there was scarcely any other individual who could have carried
this very difficult investigation so far as it was carried by Scheele.
15. In 1783 appeared his observations on the _sweet principle of oils_.
He observed, that when olive oil and litharge are combined together,
a sweet substance separates from the oil and floats on the surface.
This substance, when treated with nitric acid, yields _oxalic acid_. It
was therefore closely connected with sugar in its nature. He obtained
the same sweet matter from linseed oil, oil of almonds, of rape-seed,
from hogs' lard, and from butter. He therefore concluded that it was a
principle contained in all the expressed or fixed oils.
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