The History of Chemistry, Volume 2 (of 2)Thomson, Thomas
History
The History of Chemistry, Volume 2 (of 2)
Thomson, Thomas
Chemistry -- History
14. In the Mem. de l'Académie, for 1780 (published in 1784), we have
a paper, by Lavoisier, "On certain Fluids which may be obtained in
an aeriform State, at a degree of Heat not much higher than the mean
Temperature of the Earth." These fluids are sulphuric ether, alcohol,
and water. He points out the boiling temperature of these liquids, and
shows that at that temperature the vapour of these bodies possesses
the elasticity of common air, and is permanent as long as the high
temperature continues. He burnt a mixture of vapour of ether and oxygen
gas, and showed that during the combustion carbonic acid gas is formed.
Lavoisier's notions respecting these vapours, and what hindered the
liquids at the boiling temperature from being all converted into vapour
were not quite correct. Our opinions respecting steam and vapours in
general were first rectified by Mr. Dalton.
15. In the Mem. de l'Académie, for 1780, appeared also the celebrated
paper on _heat_, by Lavoisier and Laplace. The object of this paper was
to determine the specific heat of various bodies, and to investigate
the proposals that had been made by Dr. Irvine for determining the
point at which a thermometer would stand, if plunged into a body
destitute of heat. This point is usually called the real zero.
They begin by describing an instrument which they had contrived to
measure the quantity of heat which leaves a body while it is cooling
a certain number of degrees. To this instrument they gave the name of
_calorimeter_. It consisted of a kind of hollow, surrounded on every
side by ice. The hot body was put into the centre. The heat which it
gave out while cooling was all expended in melting the ice, which was
of the temperature of 32°, and the quantity of heat was proportional
to the quantity of ice melted. Hence the quantity of ice melted, while
equal weights of hot bodies were cooling a certain number of degrees,
gave the direct ratios of the specific heats of each. In this way they
obtained the following specific heats:
Specific heat.
Water 1
Sheet-iron 0·109985
Glass without lead (crystal) 0·1929
Mercury 0·029
Quicklime 0·21689
Mixture of 9 water with 16 lime 0·439116
Sulphuric acid of 1·87058 0·334597
4 sulphuric acid, 3 water 0·603162
4 sulphuric acid, 5 water 0·663102
Nitric acid of 1·29895 0·661391
9⅓ nitric acid, 1 lime 0·61895
1 saltpetre, 8 water 0·8167
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