Pasteur, Louis, 1822-1895; Scientists -- France -- Biography
“You remember what I used to say to you and to M. Dumas, that almost
certainly the first operation which tartar goes through in certain
factories causes it to lose all or nearly all its racemic acid. Well, in
the two Viennese factories, it is only two years since they began to
operate on crude tartar, and it is only two years since they first saw
the supposed sulphate of potash, the supposed sulphate of magnesia. For,
at M. Seybel’s, they had taken for sulphate of magnesia the little
crystals of racemic acid.
“Shortly, this is as far as I have come--I spare you many details:--
1. “The Naples tartar contains racemic acid.
2. “The Austrian tartar (neighbourhood of Vienna) contains racemic acid.
3. “The tartars of Hungary, Croatia, Carniola contain racemic acid.
4. “The tartar of Naples contains notably more than the latter, for it
presents racemic acid even after one refining process, whilst that from
Austria and Hungary only presents it when in the crude state.
“I believe it now to be extremely probable that I shall find some
racemic acid in French tartars, but in very small quantities; and if it
is not detected it is because all the circumstances of the manufacture
of tartaric acid are unknown or unappreciated, or because some little
precaution is neglected that would preserve it or make it visible.
“You see, dear Marie, how useful was my journey.”
“_Vienna, September 30, 1852._ I am not going to Trieste; I shall start
for Prague this evening.”
“_Prague, October 1, 1852._ Here is a startling piece of news. I arrive
in Prague; I settle down in the Hôtel d’Angleterre, have lunch, and call
on M. Rochleder, Professor of chemistry, so that he may introduce me to
the manufacturer. I go to the chemist of the factory, Dr. Rassmann, for
whom I had a letter from M. Redtenbacher, his former master. That letter
contained all the questions that I usually make to the manufacturers of
tartaric acid.
“Dr. Rassmann hardly took time to read the letter; he saw what it dealt
with, and said to me: ‘I have long obtained racemic acid. The Paris
Pharmaceutical Society offered a prize for whoever manufactured it. It
is a product of manufacture; I obtain it with the assistance of tartaric
acid.’ I took the chemist’s hand affectionately, and made him repeat
what he had said. Then I added: ‘You have made one of the greatest
discoveries that it is possible to make in chemistry. Perhaps you do not
realise as I do the full importance of it. But allow me to tell you
that, with my ideas, I look upon that discovery as impossible. I do not
ask for your secret; I shall await the publication of it with the
greatest impatience. So that is really true? You take a kilogramme of
pure tartaric acid, and with that you make racemic acid?’
“‘Yes,’ he said; ‘but it is still’ ... and as he had some difficulty in
expressing himself, I said: ‘It is still surrounded with great
difficulties?’
“‘Yes, monsieur.’
Public-domain text, read in full here on John Shaqi.
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