The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
In the Royal Institution Journal already noticed, we find several
communications from him, under the titles of "Observations on
different methods of obtaining Gallic Acid;"--"On the processes
of Tanning," &c. All the new facts however, discovered in the
course of his experiments, were embodied in a long and elaborate
memoir, which was read before the Royal Society on the 24th of
February 1803, and published in the Philosophical Transactions
for that year. It was entitled "An Account of some Experiments
and Observations on the constituent parts of certain astringent
Vegetables, and on their operation in Tanning. By Humphry Davy,
Professor of Chemistry in the Royal Institution. Communicated by
the Right Honourable Sir Joseph Banks, P. R. S."
Although Seguin and Proust had already examined many of the
properties of that vegetable principle to which the name of
_tannin_ had been given, yet its affinities had been but little
examined; and the manner in which its action upon animal matters
may be modified by combination with other substances, had been
still less considered.
His principal design in this enquiry was to elucidate the practical
part of the art of tanning skins, so as to form leather; but
in pursuing this object, he was necessarily led into chemical
investigations connected with the analysis of the various bodies
containing the tanning principle, and the peculiar properties and
value of each.
The vegetable principles that had been regarded as more usually
present in astringent infusions, are _tannin_, _gallic acid_,
and _extractive matter_. In attempting to ascertain the relative
proportions of _tannin_ contained in different infusions, Davy was
led, after various trials, to prefer the generally received method
of precipitating by means of _gelatine_ procured from isinglass. In
using this test, however, he discovered that several precautions
were necessary;--that the solution should be quite fresh,--that
it should be as much saturated as may be compatible with its
fluidity,--and that the precipitate obtained should be reduced to a
uniform degree of dryness.
It is evident that if the quantity of gelatine in the solution,
employed as the precipitant, be known, it will only be necessary to
ascertain the weight of the precipitate produced by it, in order to
learn the absolute proportion of tannin present in any specimen.
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