The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
He details the results of a number of experiments made upon galls,
and ascertains the relative proportions of their several elements;
and he proves that tannin may exist in such a state of combination
in different substances as to elude the test of gelatine; in which
case, to detect its presence, it is necessary to have recourse to
the action of the diluted acids.
Sir Joseph Banks had concluded, from the sensible properties of
_catechu_,[44] or _terra Japonica_, that it was rich in tannin:
Davy confirmed this opinion by experiment. The leather tanned by
it appeared to possess the same qualities as when tanned in the
usual manner; and although this substance contains a small portion
of extractive matter, yet the increase of weight of the skin was
rather less than when solutions of galls were used.
[44] Catechu is an extract obtained from the wood of a species
of the _Mimosa_ that grows in India, by boiling and subsequent
evaporation. It is of two kinds; one from Bengal, the other from
Bombay. The former contains rather less, the latter rather more,
than half its weight of tannin. The remainder in both cases is a
peculiar extractive matter mixed with mucilage.--P.
In examining different barks, he was not able to procure from them
any free gallic acid, but their infusions gave, on evaporation,
tannin and extractive. The greater number of his experiments were
made on the barks of the oak, the Leicester willow, the Spanish
chestnut, the elm, and the common willow. The largest quantity of
tannin he found to be contained in the interior, or white cortical
layers; and the largest quantity of extractive matter in the
exterior layers; the epidermis, or rough outward bark, did not
contain either the one or the other.
From his general observations he is inclined to suppose that, in
all the astringent vegetables, the tannin is of the same species,
and that all the differences attributed to it depend upon its state
of combination with other principles.
In applying the results of his experiments to the theory of
tanning, he considers the process as simply depending upon the
union of the tannin with the matter of the skin, in such a manner
as to form with it an insoluble compound. Gallic acid, he feels
assured, does not produce any notable effects in the process; but
he thinks that the quality of the leather depends, in some degree,
upon the quantity of extractive matter it may imbibe.
Skin, combined with extractive matter only, would be increased in
weight, become coloured, and be extremely flexible, but it would
not be insoluble in water; and were it combined with tannin alone,
it would be heavier and less supple than when both these principles
enter into the compound.
He examines with great acuteness and precision some of the more
popular opinions entertained by tanners, and brings his science to
bear very satisfactorily upon several of their processes.
Public-domain text, read in full here on John Shaqi.
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