The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
In every case in which he had procured much soda, the glass[61] at
the point of contact with the wire seemed considerably eroded; when
by substituting an agate for a glass cup, no fixed saline matter
could be obtained. Its source therefore, in the former case, was
evidently the glass.
[61] It is perhaps a fact not very generally known, that glass,
to a certain extent, is decomposable by water: if some of it in
a powdered state be triturated with distilled water, in a short
time the turmeric test will indicate a portion of alkali in
solution.
With respect to Mr. Sylvester's experiment, already noticed, it
was sufficient to say that he conducted his process in a vessel of
_pipe-clay_, which not only contains lime, but may also include in
its composition some of the combinations of a fixed alkali.
On resuming the enquiry, it was Davy's first care to remove
every possible source of impurity: he accordingly procured cups
of agate, which, previously to being filled, were boiled for
several hours in distilled water; and a piece of very white and
transparent _amianthus_, a substance first proposed for this
purpose by Dr. Wollaston, having been similarly purified, was made
to connect the vessels together. Thus was every apparent source of
fallacy removed; but still, after having been exposed to Voltaic
action for forty-eight hours, the water in the positive cup gave
indications of muriatic acid, and that in the negative cup, of
soda! The result was as embarrassing as it was unexpected; but it
was far from convincing him that the bodies thus obtained were
_generated_:--but whence arose the saline matter? Did the agate,
after every precaution, still contain some very minute portion
of saline matter, not easily discoverable by chemical tests? To
determine this question, the experiment was repeated a second,
a third, and a fourth time: the quantities of saline matter
diminished in every successive operation, which sufficiently proved
that the agate must at least have been _one_ of the sources sought
for; but four additional repetitions of the process convinced
the operator that it could not be the only one; that there must
exist some other source from which the alkali proceeded, since
it continued to appear to the last, in quantities sufficiently
distinct, and apparently equal, in every experiment. This was
extremely perplexing: every precaution had been taken--the agate
cups had even been included in glass vessels, out of the reach of
the circulating air--all the acting materials had been repeatedly
washed with distilled water; and no part of them in contact with
the fluid had ever touched the fingers.
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