The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
In the most simple case of electrical action, the alkali which
receives electricity from the metal would necessarily, on being
separated from it, appear _positive_; whilst the acid, under
similar circumstances, would be _negative_; and these bodies having
respectively, with regard to the metal, that which may be called a
positive and a negative electrical energy, in their repellent and
attractive functions, would seem to be governed by the common laws
of electrical attraction and repulsion; the body possessing the
positive energy being repelled by positively electrified surfaces,
and that possessing the negative influence following the contrary
order.
Davy made a number of experiments with the view of elucidating this
idea, and of extending its application; and, in all cases, their
results tended, in a most remarkable manner, to confirm the analogy.
He proceeded, by means of very delicate instruments, to ascertain
the electrical states of single insulated acid and alkaline
solutions, after their contact with metals; but the sources of
errors were so numerous, as to render the results far from being
satisfactory; but in experiments on dry and solid bodies, the
embarrassments arising from evaporation, chemical action, &c. did
not occur. When perfectly dry oxalic, succinic, benzoic, or boracic
acid, either in the form of powder or crystals, were touched upon
an extended surface with a plate of copper, insulated by a glass
handle, the copper was found positive, the acid negative. When
again metallic plates were made to touch dry lime, strontia, or
magnesia, they became negative: in these latter experiments the
effect was exceedingly satisfactory and distinct; a single contact
upon a large surface being sufficient to communicate a considerable
charge.
Numerous other trials were made, and the results confirmed the
principle; and moreover proved, as might have been expected, that
bodies possessing electrical conditions with regard to one and the
same body, possessed them with regard to each other: for instance,
a dry piece of lime became positively electrical by repeated
contact with crystals of oxalic acid.
These results led him to reason more fully upon the "Relations
between the Electrical energies of bodies and their Chemical
affinities."
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