The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
His first attempts were made on solutions of the alkalies; but,
notwithstanding the intensity of the electric action, the
water alone underwent decomposition, and oxygen and hydrogen
were disengaged with the production of much heat, and violent
effervescence. The presence of water thus appearing to prevent the
desired decomposition, potash, in a state of igneous fusion, was
in various ways submitted to experiment; when it was evident that
combustible matter of some kind, burning with a vivid light, was
given off at the negative wire. After numerous trials, during the
progress of which the difficulties which successively arose were
as immediately combated by ingenious manipulation, a small piece
of potash sufficiently moistened, by a short exposure to the air,
to give its surface a conducting power, was placed on an insulated
disc of platina, connected with the negative side of the battery in
a state of intense activity, and a platina wire communicating with
the positive side, was at the same instant brought into contact
within the upper surface of the alkali.--Mark what followed!--A
series of phenomena, each of which the reader will readily
understand as it is announced,--for it will be in strict accordance
with the laws which Davy had previously established:--the potash
began to fuse at both its points of electrization: a violent
effervescence commenced at the upper, or positive surface; while
at the lower, or negative one, instead of any liberation of
elastic matter, which would probably have happened had hydrogen
been an element of the alkaline body, small globules, resembling
quicksilver, appeared, some of which were no sooner formed than
they burnt with explosion and bright flame.--What must have been
the sensations of Davy at this moment!--He had decomposed potash,
and obtained its base in a metallic form.
The gaseous matter developed, during the experiment, at the
positive pole of the apparatus, he very shortly identified as
oxygen. To collect, however, the metallic matter, in a quantity
sufficient for a satisfactory examination, was by no means so easy;
for, like the _Alkahest_ imagined by the Alchemist, it acted more
or less upon every body to which it was exposed; and such was its
attraction for oxygen, that it speedily reverted to the state of
alkali by recombining with it.
After various trials, however, it was found that recently distilled
naphtha presented a medium in which it might be preserved and
examined, since a thin transparent film of this fluid, while it
defended the metal from the action of the atmosphere, did not
oppose any obstacle to the investigation of its physical properties.
Thus provided, he proceeded to enquire into the nature of the
new and singular body, to which he afterwards gave the name of
POTASSIUM, and which may be described as follows.
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