The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
[73] If we are disposed to enter into a more critical examination
of the subject, we shall find that, although the above is a
general expression of the change produced, there are subordinate
actions of a more complicated nature: the metal, in the first
place, decomposes a portion of the water, in order to combine
with its oxygen, and form potash, which in its turn has a
powerful affinity for water; the heat arising from two causes,
decomposition and combination, is sufficiently intense to produce
the inflammation. Water is a bad conductor of heat; the globule
swims exposed to air; a part of which is dissolved by the heated
nascent hydrogen; and this gas, being capable of spontaneous
inflammation, explodes and communicates the effect of combustion
to any of the bases that may be yet uncombined. The manner in
which the potassium runs along the surface of water may be
compared to a drop of water on red-hot iron; in the one case the
hot potassium, in the other the cold water, is enveloped in an
atmosphere of steam.
One of the neatest modes of showing the production of alkali,
in the decomposition of water by the basis of potash, consists
in dropping a globule of potassium upon moistened paper tinged
with turmeric. At the moment that it comes into contact with the
water, it burns and moves rapidly upon the paper, as if in search
of moisture, leaving behind it a deep reddish-brown trace of its
progress, and acting upon the test paper precisely as dry caustic
potash.
From these observations, the reader will immediately perceive,
that the decomposition of the fixed alkalies has placed in the
hands of the experimentalist a new instrument of research, scarcely
less energetic, or of less universal application, than the power
from which the discovery emanated. Davy observes upon this point,
that "it will undoubtedly prove a powerful agent for analysis,
and having an affinity for oxygen, stronger than any other known
substance, it may possibly supersede the application of electricity
to some of the undecompounded bodies." So strong indeed is its
affinity for oxygen, that it discovers and decomposes the small
quantities of water contained in alcohol and ether; and in the
latter case, this decomposition is connected with an instructive
result. Potash is insoluble in that fluid: when therefore its base
is thrown into it, oxygen is furnished, hydrogen gas disengaged,
and the alkali, as it is regenerated, renders the ether white and
turbid.
But perhaps the most beautiful illustration of its deoxidizing
power is afforded by its action on carbonic acid gas, or fixed
air: when heated in contact with that gas, it catches fire, and by
uniting with its oxygen, becomes potash, while the liberated carbon
is deposited in the form of charcoal.
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