The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
It is scarcely necessary to state, that the presence of carbon was
readily traced to sources of impurity. The hypothesis which assumed
the existence of hydrogen as an element, was not so easily refuted.
It was espoused by MM. Gay Lussac, Thénard, and Ritter, on the
Continent, and by Mr. Dalton in England. The former derived their
inference from the action of potassium upon ammonia, by which
they obtained a fusible substance that yielded by heat more
hydrogen than the ammonia contained; the latter contended that
potassium and sodium are proved to be _hydrurets_, by the very
process employed for their production; for, since common potash is
a _hydrat_, and oxygen is produced at one surface, and potassium
at the other, by Voltaic action, he conceived that the former
arose from the decomposition of water, and that the hydrogen
must therefore unite with the potash to form potassium. It is a
curious fact, that Berthollet, in the very sentence in which he
insisted upon the excessive quantity of hydrogen disengaged in
his experiment, as a proof that potassium must be a _hydruret_,
should have stated that the addition of water to the residuum was
necessary for obtaining his result. How could it have happened
that he overlooked so obvious a source of hydrogen? Mr. Dalton, as
well as Ritter, considered the low specific gravity as favouring
the idea of their containing hydrogen; but Davy observes that they
are less volatile than antimony, arsenic, and tellurium, and much
less so than mercury. Besides, sodium absorbs much more oxygen
than potassium, and, on the hypothesis of hydrogenation, must
therefore contain more hydrogen; and yet though soda is said to be
lighter than potash, in the proportion of thirteen to seventeen
nearly, sodium is heavier than potassium, in the proportion of
nine to seven at least. On the theory of Davy, this circumstance
is what ought to have been expected. Potassium has a much stronger
affinity for oxygen than sodium, and must condense it much more;
and the resulting higher specific gravity of the combination is
a necessary consequence. In this manner did Davy entangle his
opponents in their own arguments, and establish, in the most
triumphant manner, the truths of his original views.
Thus then was a discovery effected, and at once rendered
complete, which all the chemists in Europe had vainly attempted
to accomplish. The alkalies had been tortured by every variety of
experiment which ingenuity could suggest, or perseverance perform,
but all in vain; nor was the pursuit abandoned until indefatigable
effort had wrecked the patience and exhausted every resource of the
experimentalist. Such was the disheartening, and almost forlorn
condition of the philosopher when Davy entered the field:--he
created new instruments, new powers, and fresh resources; and
Nature, thus interrogated on a different plan, at once revealed her
long cherished secret.
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