The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
The discovery of potassium led to that of the true nature of what
had been long familiar to chemists by the name of _pure Potash_,
but which ought to have been called the _hydrat_, for the _pure_
alkali was not known until after the discovery of Davy. The
experiments of MM. Gay Lussac and Thénard have shown this substance
to be a _Protoxide_. It is difficult of fusion; it has a grey
colour and a vitreous fracture, and dissolves in water with much
heat. The _Peroxide_ is procured by the combustion of potassium at
a low temperature; it had been observed by Davy in October 1807,
but at that time he supposed it to be the oxide containing the
smallest proportion of oxygen: it has a yellow colour, and when
thrown into water effervesces, and gives out oxygen gas.[81] When
heated very strongly upon platina, oxygen is also expelled from it,
and there remains the _protoxide_, or pure potash.
[81] The 'Potassa Fusa' of our Pharmacopoeia generally contains a
small proportion of the peroxide, and will therefore effervesce
when thrown into water.
It was a great object with Davy, to show that the product resulting
from the combustion of potassium, was a pure oxide free from
water; for it is evident that had potassium been a _Hydruret_, its
combustion must have produced a _Hydrat_. This he accomplished by a
series of experiments which he performed in the laboratory of Mr.
Children, and which are published in his Bakerian Lecture of 1800.
Having discovered the presence of oxygen in the fixed alkalies, he
was naturally led by analogy to enquire whether ammonia might not
also contain it. It was true that the chemical composition of that
body had been considered as satisfactorily settled, and that the
conversion of it into hydrogen and nitrogen, in the experiments of
Scheele, Priestley, and Berthollet, had left nothing farther to be
accomplished. All new facts, however, are necessarily accompanied
by a new train of analogies; and Davy, in perusing the accounts of
the various experiments to which ammonia had been submitted, tells
us that he saw no reason for considering the presence of oxygen
as impossible; for, supposing hydrogen and nitrogen to exist in
combination with oxygen in low proportion, this latter principle
might easily disappear in the analytical experiments by heat and
electricity, in the form of water deposited upon the vessels
employed, or dissolved in the gases produced.
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