The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)Paris, John Ayrton
Science
The Life of Sir Humphry Davy, Bart. LL.D., Volume 1 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
Supposing that a similar kind of action might assist the
decomposition of the alkaline earths, he proceeded to institute a
series of experiments upon that principle; and the results were
more satisfactory than those obtained by the preceding methods
of experimenting--a compound was obtained which acted upon water
with the evolution of hydrogen, producing a solution of the
earth, and leaving free the tin, or lead, with which its base may
be supposed to have been alloyed;--but in all such experiments
the quantity of the metallic basis produced must have been very
minute, and its character very questionable.
In this stage of the enquiry, Davy received the letter from
Professor Berzelius of Stockholm, the contents of which he
embodied in his memoir, accompanied with such observations as his
own information suggested.
"A globule of mercury, electrified by the power of a battery
consisting of five hundred pairs of double plates of six inches
square, weakly charged, was made to act upon a surface of
slightly moistened barytes, fixed upon a plate of platina. The
mercury gradually became less fluid, and after a few minutes was
found covered with a white film of barytes; and when the amalgam
was thrown into water, hydrogen was disengaged, the mercury
remained free, and a solution of barytes was formed.
"The result with lime, as these gentlemen had stated, was
precisely analogous.
"That the same happy methods must succeed with strontites and
magnesia, it was not easy to doubt, and I quickly tried the
experiment. From strontites I obtained a very rapid result; but
from magnesia, in the first trials, no amalgam could be procured.
By continuing the process, however, for a longer time, and
keeping the earth continually moist, at last a combination of the
bases with mercury was obtained, which slowly produced magnesia,
by absorption of oxygen from air, or by the action of water.
"All these amalgams I found might be preserved for a considerable
period under naphtha. In a length of time, however, they became
covered with a white crust under this fluid. When exposed to
air, a very few minutes only were required for the oxygenation
of the bases of the earths. In the water the amalgam of barytes
was most rapidly decomposed; that of strontites, and that of lime
next in order: but the amalgam from magnesia, as might have been
expected from the weak affinity of the earth for water, very
slowly changed: when, however, a little sulphuric acid was added
to the water, the evolution of hydrogen, and the production and
solution of magnesia, were exceedingly rapid, and the mercury
soon remained free."
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