The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)Paris, John Ayrton
History
The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
He was, in the first instance, led to suspect the accuracy of those
conclusions at which Mr. Walsh and Mr. Morgan had arrived, from
considering that, "in the most perfect vacuum which can be obtained
in the Torricellian tube, vapour of mercury, though of extremely
small density, must still always exist." I propose to follow our
philosopher through the paths of this enquiry; and then, with all
the deference due to such high authority, to state the objections
which may be urged against his results.
First, then, as to the results he obtained with quicksilver in
an apparatus simple, but well adapted at once to insure the most
completely attainable vacuum, and to exhibit its capability of
receiving a charge. In all cases where this vacuum was perfect,
he found it to be permeable to electricity, and to be rendered
luminous, either by the common spark, or by the shock from a Leyden
jar; and, moreover, that the coated glass surrounding it became
charged under such circumstances; but the intensity of the light in
these experiments was always in proportion to the temperature, or,
in other words, to the density of the mercurial vapour; and that
at 20° below zero of Fahrenheit, it became so faint as to require
considerable darkness to render it perceptible.
The great brilliancy, on the other hand, of the electrical light
in pure, dense vapour of mercury, was beautifully displayed during
the operation of boiling the metal in an exhausted tube. "In the
formation and condensation of the globules of mercurial vapour, the
electricity produced by the friction of the mercury against the
glass, was discharged through the vapour with sparks so bright as
to be visible in daylight."
The charge likewise communicated to the tinfoil was higher, the
higher the temperature; at 0° Fahrenheit it was extremely feeble.
This, like the phenomenon of the electric light, must, he thinks,
depend upon the different density of the vapour of mercury.
But he was desirous of still farther refining his experiments,
so as to exclude, as far as it was possible, the presence of any
volatile matter; and in this part of the enquiry he displayed,
in a very masterly manner, that happy talent in which he so
far surpassed his contemporaries, of suggesting expedients
and contriving new apparatus in order to vanquish practical
difficulties.
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