The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)Paris, John Ayrton
History
The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
[81] The results are contained in a short paper in the Quarterly
Journal of Science, vol. xv.
On exposing the hydrate, in a tube hermetically sealed, to a
temperature of 100°, the substance fused, the tube became filled
with a bright yellow atmosphere, and, on examination, was found
to contain two fluid substances: the one, about three-fourths of
the whole, was of a faint yellow colour, having very much the
appearance of water; the remaining fourth was a heavy, bright
yellow fluid, lying at the bottom of the former, without any
apparent tendency to mix with it.
By operating on the hydrate in a bent tube hermetically sealed,
Mr. Faraday found it easy, after decomposing it by a heat of 100°,
to distil the yellow fluid to one end of the tube, and thus to
separate it from the remaining portion. If the tube were now cut in
the middle, the parts flew asunder, as if with an explosion, the
whole of the yellow portion disappeared, and there was a powerful
atmosphere of chlorine produced; the pale portion, on the contrary,
remained, and when examined, proved to be a weak solution of
chlorine in water, with a little muriatic acid, probably from the
impurity of the hydrate used. When that end of the tube in which
the yellow fluid lay was broken under a jar of water, there was an
immediate production of chlorine gas.
After several conjectures as to the nature of the changes thus
produced, Mr. Faraday arrived at its true explanation; viz. that
the chlorine had been entirely separated from the water by the
heat, and condensed into a dry fluid by the mere pressure of its
own abundant vapour. He subsequently confirmed these views by
condensing chlorine in a long tube, by mechanical pressure, applied
by means of a condensing syringe, and which farther enabled him to
ascertain that the degree of pressure necessary for this effect was
about that of four atmospheres.
To Mr. Faraday's paper upon this subject, published in the
Philosophical Transactions for the year 1823, Sir Humphry Davy
thought proper to add a "Note on the condensation of muriatic acid
gas into the liquid form."
The circumstances under which this was effected are briefly these.
On the morning (Thursday, March 6th,) after Mr. Faraday had
condensed chlorine, Sir Humphry Davy had no sooner witnessed the
result, than he called for a strong glass tube, and, having placed
in it a quantity of muriate of ammonia and sulphuric acid, and then
sealed the end, he caused them to act upon each other, and thus
condensed the muriatic acid, which was evolved, into a liquid. The
condensation of carbonic acid gas, nitrous oxide gas, and several
others, were in succession treated with similar success; but, as I
regard the discovery as strictly belonging to Mr. Faraday, I shall
confine myself to the relation of those experiments and deductions
which, with equal justice, I must assign to Sir Humphry Davy.
Public-domain text, read in full here on John Shaqi.
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