The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)Paris, John Ayrton
History
The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
The identity of Phlogiston in all combustible bodies was founded
upon observations and experiments of so decisive a nature, that
after the existence of the principle itself was admitted, they
could not fail to be satisfactory. When phosphorus is made to
burn, it gives out a strong flame, much heat is evolved, and the
phosphorus is dissipated in fumes, which, if properly collected,
will quickly absorb moisture from the atmosphere, and produce
an acid liquid known by the name of phosphoric acid. Phosphorus
then must consist, say the Stahlians, of Phlogiston and this acid.
Again--If this liquid be evaporated to a dry substance, mixed with
a quantity of charcoal powder, and then heated in a vessel from
which the external air is excluded, a _portion_, or the _whole_ of
the charcoal will disappear, and phosphorus will be reproduced,
possessing all the properties that it had before it was subjected
to combustion. In this case, it was supposed that the charcoal
restored the phlogiston. There was much plausibility in all this,
as well as in the reasoning which followed. Since we may employ,
with equal success, any kind of combustible body for the purpose
of changing phosphoric acid into phosphorus, such as lamp-black,
sugar, resin, or even several of the metals, it was concluded that
all such bodies contain a common principle which they communicate
to the phosphoric acid; and since the new body formed is in all
cases identical, the principle communicated must also be identical.
Hence combustible bodies contain an identical principle, and this
principle is Phlogiston.
The same theory applied with equal force to the burning of sulphur
and several of the metals, and to their reconversion by combustible
bodies.
When lead is kept nearly at a red-heat in the open air for some
time, it is converted into a pigment called _red lead_; this is a
calx of lead. To restore this calx again to metallic lead, it is
only necessary to heat it in contact with almost any combustible
matter; all these bodies therefore must contain one common
principle, which they communicated to the red lead, and by so doing
reconverted it to the state of metal. Metals then were regarded
as compounds of _calces_ and phlogiston. Thus far the theory
works glibly enough; but now comes a startling fact, which was
long unnoticed by the blind adherents of Stahl, or, if noticed,
intentionally overlooked. It was observed very early, that when a
metal was converted into a calx, its weight was increased. When
this difficulty first forced itself upon the attention of the
Phlogistians, it was necessary that they should either explain it,
or at once abandon their theory. They accordingly endeavoured to
evade the difficulty, not only by asserting that phlogiston had no
weight, but that it was actually endowed with a principle of levity.
Public-domain text, read in full here on John Shaqi.
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