The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)Paris, John Ayrton
History
The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
Mr. Kirwan attempted to answer it, and to prove that phlogiston is
no other than hydrogen.
This opinion, which Mr. Kirwan informs us was first suggested
by the discoveries of Dr. Priestley, met with a very favourable
reception from the chemical world, and was adopted, amongst many
others, by Mr. Cavendish. The object of Mr. Kirwan was to prove,
that hydrogen exists as a component part of every combustible body;
that during combustion it separates from the combustible body, and
combines with the oxygen of the air. At the same time, Lavoisier
was engaged in examining the experiment of Bayen, and those of
the British philosophers. Bayen, in 1774, had shown that mercury
converted into a calx, or earth, by the absorption of air, could
be revived without the addition of any inflammable substance; and
hence he concluded, that there was no necessity for supposing
the existence of any peculiar principle of inflammability, in
order to account for the calcination of metals; but he formed no
opinion respecting the nature of the air produced from the _calx_
of mercury. Lavoisier, in 1775, showed that it was an air, which
supported flame and respiration better than common air, which he
afterwards named oxygen: the same substance that Priestley and
Scheele had procured from other metallic bodies the year before,
and had particularly described.
Lavoisier also discovered that the same air is produced during the
revivification of metallic calces by charcoal, as that which is
emitted during the calcination of limestones; hence he concluded,
that this elastic fluid is composed of oxygen and charcoal: and
from his experiments on nitrous acid and oil of vitriol, he also
inferred that this gas entered into the composition of these
substances.
Lavoisier was now enabled to explain the phenomena of combustion,
without having recourse, to phlogiston: a principle merely supposed
to exist, because combustion could not be explained without it.
His new theory depends upon the two laws discovered by himself
and Dr. Black; _viz._ that when a combustible is raised to a
certain temperature, it begins to combine with the oxygen of the
atmosphere, and that this oxygen during its condensation lets go
the _latent_ caloric, and the light with which it was combined
while in the gaseous state. Hence their appearance during every
combustion. Hence also the change which the combustible undergoes
in consequence of combustion.
It followed from this view, that the metallic _calces_ were
combinations of metals with oxygen; and on examining the products
of certain inflammable bodies, and finding them to be acid, the
conclusion was extended by a plausible analogy to other acids whose
bases were unknown, and the general proposition was established
that oxygen was the universal principle of acidity; that acids
resulted from the union of a peculiar combustible base, called the
_radical_, with the common principle, oxygen, technically termed
the _acidifier_.
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