The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)Paris, John Ayrton
History
The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
Thus, then, has the _acidifying_ hypothesis of Lavoisier been
overturned, and a new theory constructed out of its ruins, which
acknowledges no distinct element as the one imparting to matter the
characters of an acid.
Equally complete has been the downfall of the theory of combustion.
The discovery of the true nature of chlorine was, in itself,
sufficient to show that bodies might combine, with the phenomena
of heat and light, without the presence of oxygen; but Davy has
brought a mass of evidence from other sources in proof of the
same truth. He has shown that, whenever the chemical forces which
determine either composition or decomposition are energetically
exercised, the phenomena of combustion, or incandescence, with a
change of properties, are displayed. He has therefore annulled the
distinction between supporters of combustion and combustibles,
since he has shown that, in fact, one substance frequently acts in
both capacities, being a supporter _apparently_ at one time, and a
combustible at another. But in both cases the heat and light depend
on the same cause, and merely indicate the energy and rapidity
with which reciprocal attractions are exerted. Thus sulphuretted
hydrogen is a combustible with oxygen and chlorine; a supporter
with potassium. Sulphur, with chlorine and oxygen, has been called
a combustible basis; with metals, it acts the part of a supporter.
In like manner, potassium unites so powerfully with arsenic and
tellurium, as to produce the phenomena of combustion. Nor can
we ascribe the appearances to the liberation of latent heat, in
consequence of condensation of volume. The protoxide of chlorine,
a body destitute of any combustible constituent, at the instant of
decomposition evolves light and heat with explosive violence; and
its volume becomes one-fifth greater. Chloride and iodide of azote,
compounds alike destitute of any inflammable matter, according to
the ordinary belief, are resolved into their respective elements
with tremendous force of inflammation; and the first expands
into more than six hundred times its bulk. Now, instead of heat
and light, a prodigious degree of _cold_ ought to accompany such
an expansion, according to the hypothesis of latent heat. Other
instances might be cited, and other arguments adduced on the same
subject, but time and space fail me.[134]
[134] The reader who wishes for further details, will consult
with advantage the article Combustion in Dr. Ure's Dictionary of
Chemistry; a work to which I acknowledge myself much indebted on
this and other occasions.
Such, then, are the facts developed by the experimental researches
of Sir Humphry Davy; from which it follows, that--
1. Combustion is not necessarily dependent on the agency of oxygen.
2. That it cannot be regarded as dependent upon any peculiar
principle or form of matter, but must be considered as a general
result of intense chemical action.
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