The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)Paris, John Ayrton
History
The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
He confirms the opinion of Dr. Henry, and other chemists, as to
the fire-damp being light carburetted hydrogen gas, and analogous
to the inflammable gas of marshes; but he found that the degree
of its combustibility differed most materially from that of the
other common inflammable gases, which it is well known will
explode by the contact of both red-hot iron and charcoal; whereas
well-burned charcoal, ignited to the strongest red heat, did not
explode any mixture of the air and of the fire-damp; and a fire
made of well-burned charcoal, that is to say, of charcoal that
will burn without flame, was actually blown up to whiteness by
an explosive mixture containing the fire-damp without producing
its inflammation.[31] An iron rod also, at the highest degree of
_red_ heat, and even at the common degree of _white_ heat, did not
inflame explosive mixtures of the fire-damp; but when in brilliant
combustion, it produced the effect.
[31] Whence he observes that, if it be necessary to be present
in a part of the mine where the fire-damp is explosive, for the
purpose of clearing the workings, taking away pillars of coal, or
other objects, the workmen may be safely lighted by a fire made
of charcoal, which burns without flame.
He moreover found that the heat produced by the combustion of
the fire-damp was much less than that occasioned by most other
inflammable gases under similar circumstances; and hence its
explosion was accompanied with comparatively less expansion:
a circumstance of obvious importance in connection with the
propagation of its flame.
Numerous experiments were likewise instituted by him with a view
to determine the proportions of air with which the fire-damp
required to be mixed, in order to produce an explosive atmosphere;
and he found the quantity necessary for that purpose to be very
considerable; even when mixed with three or nearly four times its
bulk of air, it burnt quietly in the atmosphere, and extinguished
a taper. When mixed with between five and six times its volume of
air, it exploded freely. The mixture which seemed to possess the
greatest explosive power was that of seven or eight parts of air to
one of gas.
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