The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)Paris, John Ayrton
History
The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
In a paper read before the Royal Society, on the 23rd of January
1817, entitled, "Some new Experiments and Observations on the
Combustion of Gaseous Mixtures, with an Account of a method of
preserving a continued Light in mixtures of inflammable Gases and
Air without Flame," Sir H. Davy announces the application of a
principle which he had discovered in the progress of his researches
for increasing the utility of the Safety-lamp, and which, a century
ago, would have unquestionably exposed its author to the charge of
witchcraft.
Having ascertained that the temperature of flame is infinitely
higher than that necessary for the ignition of solid bodies,
it appeared to him probable that, in certain combinations of
gaseous bodies, although the increase of temperature might not
be sufficient to render the gaseous matters themselves luminous,
they might nevertheless be adequate to ignite solid matters
exposed to them. During his experiments on this subject, he was
led to the discovery of the curious phenomenon of slow combustion
without flame. He observes, that there cannot be a better mode
of illustrating the fact, than by an experiment on the vapour of
ether or of alcohol. Let a few coils of wire of platinum of the
one-sixtieth or one-seventieth of an inch be heated by a hot poker
or candle, and let it be brought into the glass; it will presently
become glowing, almost white hot, and will continue so, as long as
a sufficient quantity of vapour and of air remain in the glass.[36]
[36] This principle has been applied for constructing what has
been termed the _Aphlogistic Lamp_, which is formed by placing
a small coil of platinum wire round the wick of a common spirit
lamp. When the lamp, after being lighted for a few moments,
is blown out, the platinum wire continues to glow for several
hours, as long as there is a supply of spirit of wine, and to
give light enough to read by; and sometimes the heat produced
is sufficient to rekindle the lamp spontaneously. The same
phenomena are produced by the vapour of camphor; and an aromatic
fumigating lamp has lately been advertised for sale, which is no
other than the contrivance above described; and it is evident
that, if the spirit be impregnated with fragrant principles, an
aromatic vinegar will be developed during its slow combustion,
and diffused in fumes through the apartment.
This experiment on the slow combustion of ether is accompanied with
the formation of a peculiar acrid and volatile substance possessed
of acid properties, which has been particularly examined by Mr.
Daniell, who, having at first regarded it as a new acid, proposed
for it the name of _Lampic_ acid, in allusion to the researches
which led to its discovery; he has, however, since ascertained that
its acidity is owing to the acetic acid, which is combined with
some compound of carbon and hydrogen, different both from ether and
alcohol.
Public-domain text, read in full here on John Shaqi.
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