The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)Paris, John Ayrton
History
The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
[52] A short notice of them first appeared in the third number
of the "Journal of Science and the Arts," edited at the Royal
Institution.
He detects, in the first instance, the general principle of
inflammable gas, in a state of combustion, being arrested in its
progress by capillary tubes; he next applies it to the construction
of a Safety-lamp, and then, by observing the phenomena which this
lamp exhibits, is led to novel views respecting the nature and
properties of flame.--I shall endeavour to offer a popular view
of the curious and interesting truths disclosed by this latter
research.
He had observed that, when the coal gas burnt in the iron cage, its
colour was pale, and its light feeble; whereas the fact is rendered
familiar to us all by the flame of the gas lights, that in the
open air carburetted hydrogen burns with great brilliancy. Upon
reflecting on the circumstances of the two species of combustion,
he was led to believe that the cause of the superiority of the
light in the latter case might be owing to a _decomposition_ of a
part of the gas towards the interior of the flame, where the air
was in the smallest quantity; and that the consequent deposition
of charcoal might first by its _ignition_, and afterwards by its
_combustion_, contribute to this increase of light. A conjecture
which he immediately verified by experiment.[53]
[53] This theory of Davy is well illustrated by the change
produced in the flame of gas-light, when acted upon by the
wind, as may be seen during an illumination. The loss of light
under these circumstances evidently arises from the more rapid
combustion of the gas, by its more complete admixture with air;
in consequence of which the decomposition above described does
not take place.
The intensity therefore of the light of flames depends principally
upon the production and ignition of _solid_ matter in combustion,
so that heat and light are in this process independent phenomena.
These facts, Davy observes, appear to admit of many applications;
in explaining, for instance, the appearance of different flames--in
suggesting the means of increasing or diminishing their light, and
in deducing from their characters a knowledge of the composition of
their constituent parts.
The point of the inner blue flame of a candle or lamp urged by
the blow-pipe, where the heat is the greatest and the light the
least, is the point where the whole of the charcoal is burnt in
its gaseous combinations, without previous ignition. The flames
of phosphorus and of zinc in oxygen, and that of potassium in
chlorine, afford examples of intensity of light depending upon
the production of _fixed_ solid matter in combustion; while on
the contrary, the feebleness of the light of those flames, in
which gaseous and volatile matter is alone produced, is well
illustrated by those of hydrogen and sulphur in oxygen, or by that
of phosphorus in chlorine.
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