The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)Paris, John Ayrton
History
The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
[56] From a calculation of the ratio in which the density of the
atmosphere decreases with its altitude, and from that of the
relative combustibility of different bodies, it follows that
the taper would be extinguished at a height of between nine and
ten miles--hydrogen, between twelve and thirteen--and sulphur,
between fifteen and sixteen.
Hitherto he had only considered the effects of rarefaction, when
produced by the diminution of pressure; he had next to investigate
the phenomena of rarefaction when occasioned by expansion from heat.
The experiments of M. de Grotthus had apparently shown that
rarefaction by heat destroys the combustibility of gaseous
mixtures; those of Davy, however, proved that it enables them to
explode at a lower temperature.
In the progress of this research, while passing mixtures of
hydrogen and oxygen through heated tubes, the heat being still
below redness, he observed that steam was formed without any
combustion.
Here was a slow combination without combustion, as long since
observed with respect to hydrogen and chlorine, and oxygen and
metals; and he believes that such a phenomenon will happen at
certain temperatures with most substances that unite by heat. On
trying charcoal, he found that at a temperature which appeared to
be a little above the boiling point of quicksilver, it converted
oxygen pretty rapidly into carbonic acid, without any luminous
appearance, and that, at a dull red-heat, the elements of olefiant
gas combined in a similar manner with oxygen, slowly and without
explosion.
It occurred to Davy, in the progress of these experiments, that,
during this species of slow combination, although the increase of
temperature might not be sufficient to render the gaseous matters
luminous, or to produce flame, it might still be adequate to ignite
solid matters exposed to them. It was while engaged in devising
experiments to ascertain this fact, that he was accidentally led
to the discovery of the continued ignition of platinum wire,
during the slow combination of coal gas with atmospheric air;
the circumstances of which have been already related, as well as
the curious invention to which the application of the fact gave
origin.[57]
[57] See page 100 of this volume.
For this and his preceding papers on the subjects of flame and
combustion, the President and Council of the Royal Society adjudged
to Sir Humphry Davy the gold and silver medals, on the donation of
Count Rumford;[58] and never, I will venture say, did a society in
awarding a prize more faithfully comply with the intentions of its
founder.
Public-domain text, read in full here on John Shaqi.
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