The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)Paris, John Ayrton
History
The Life of Sir Humphry Davy, Bart. LL.D., Volume 2 (of 2)
Paris, John Ayrton
Chemists -- England -- Biography; Davy, Humphry, Sir, 1778-1829
Our history now proceeds to exhibit Sir Humphry Davy in quite a new
field of enquiry;--engaged in investigating, amidst the ruins of
Herculaneum, the nature and effects of the volcanic eruption which
overwhelmed that city in the reign of Titus; and in attempting, by
the resources of modern science, to unfold and to render legible
the mouldering archives which have been recovered from its
excavations, and deposited in the Museum at Naples.
Having witnessed the unsuccessful attempts of Dr. Sickler to unroll
some of the Herculaneum manuscripts, it occurred to him that a
chemical examination of their nature, and of the changes they had
undergone, might suggest some method of separating the leaves from
each other, and of rendering legible the characters impressed
upon them. On communicating this opinion to Sir Thomas Tyrwhitt,
he immediately placed at his disposal fragments which had been
operated upon by Mr. Hayter and by Dr. Sickler: at the same time,
Dr. Young presented him with some small pieces, which he himself
had formerly attempted to unroll.
Davy was very soon convinced by the products of their distillation,
that the nature of these manuscripts had been generally
misunderstood; that they had not, as was usually supposed, been
carbonized by the operation of fire, but were in a state analogous
to peat, or to Bovey coal, the leaves being generally cemented
into one mass by a peculiar substance which had formed, during the
fermentation and chemical change of the vegetable matter composing
them, in a long course of ages. The nature of this substance being
once known, the destruction of it would become a subject of obvious
chemical investigation.
It occurred to him, that as chlorine and iodine do not exert any
action upon pure carbonaceous substances, while they possess a
strong attraction for hydrogen, these bodies might probably be
applied with success for the purpose of destroying the adhesive
matter, without the possibility of injuring the letters of the
Papyri, the ink of the ancients, as it is well known, being
composed of charcoal. He accordingly exposed a fragment of a
brown manuscript, in which the layers were strongly adherent, to
an atmosphere of chlorine; there was an immediate action, the
papyrus smoked, and became yellow, and the letters appeared much
more distinct. After which, by the application of heat, the layers
separated from each other, and fumes of muriatic acid were evolved.
The vapour of iodine had a less distinct, but still a very sensible
action. By the simple application of heat to a fragment in a close
vessel filled with carbonic acid, or with the vapour of ether,
so regulated as to raise the temperature very gradually, and as
gradually to reduce it, there was a marked improvement in the
texture of the papyrus, and its leaves were more easily unrolled.
In all these preliminary trials, however, he found that the success
of the experiment absolutely depended upon the nicety with which
the temperature was regulated.
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