When coloured bodies exhibit two different colours complementary to
each other, the one seen by reflection and the other by transmission,
it is then highly probable that the colours are those of thin plates,
though there are still other optical principles to which they may be
referred. As the particles of bodies, and the medium which unites
them, or, as the different atoms of a compound body may have different
dispersive powers, while they exercise the same refractive force over a
particular part of the spectrum, the rays for which this compensation
takes place will be transmitted, while part of the complementary light
is reflected.[24] Or in cases where the refractive and dispersive
powers are the same, the reflective forces of the particles may vary
according to a different law, so that at the separating surfaces either
white or coloured light may be reflected.[25]
In those cases of colour where the reflected and the transmitted tints
are not complementary, as in _leaf-gold_, where the former is _yellow_
and the latter _green_;—in _leaf-silver_, where they are _white_
and _blue_, and in certain pieces of fir-wood, where the reflected
light is _whitish yellow_, and the transmitted light a _brilliant
homogeneous red_, we may explain the separation of the colours either
by the principles we have already laid down or by the doctrine of thin
plates. On the first principle, the colour of the reflected light,
which is supposed to be the same as that of the transmitted light, will
be modified by the law according to which the particles of the body
attract different rays out of the beam of white light. In pitch, for
example, the blue rays are first absorbed, so that at small thicknesses
the transmitted light is a fine yellow, while, by the action of a
greater thickness, the yellow itself is absorbed, and the transmitted
light is a bright homogeneous red. Now in leaf-gold the transmitted
colour of thinner films than we can obtain may be yellow, and,
consequently, the light reflected from the first strata of interrupting
faces will be yellow, and will determine the predominant tint of the
reflected light. On the Newtonian doctrine, Mr. Herschel has explained
it by saying, “that the transmitted rays have traversed the whole
thickness of the medium, and therefore undergo many more times the
action of its atoms than those reflected, especially those near the
first surface to which the brighter part of the reflected colour is
due.”
Public-domain text, read in full here on John Shaqi.
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