One of the most curious of these inquiries related to the connexion
between the refractive powers and the chymical composition of bodies.
Having measured the refractive powers and the densities of twenty-two
substances, he found that the forces which reflect and refract light
are very nearly proportional to the densities of the same bodies. In
this law, however, he noticed a remarkable exception in the case of
unctuous and sulphureous bodies, such as camphire, olive oil, linseed
oil, spirit of turpentine, and _diamond_, which have their refractive
powers two or three times greater in respect of their densities than
the other substances in the table, while among themselves their
refractive powers are proportional to their densities, without any
considerable variation. Hence he concluded that diamond “is an unctuous
substance coagulated,”—a sagacious prediction, which has been verified
in the discoveries of modern chymistry. The connexion between a high
degree of inflammability and a great refracting force has been still
more strongly established by the high refractive power which I detected
in phosphorus, and which was discovered in hydrogen by MM. Biot and
Arago.
There is no part of the optical labours of Newton which is less
satisfactory than that which relates to the double refraction of
light. In 1690, Huygens, published his admirable treatise on light,
in which he has given the law of double refraction in calcareous
spar, as deduced from his theory of light, and as confirmed by direct
experiment. Viewing it probably as a theoretical deduction, Newton
seems to have regarded it as incorrect, and though he has given Huygens
the credit of describing the phenomena more exactly than Bartholinus,
yet, without assigning any reason, he rejected the law of the Dutch
philosopher, and substituted another in its place. These observations
of our author form the subject of the twenty-fifth and twenty-sixth
queries at the end of his Optics, which was published fourteen years
after the appearance of Huygens’s work. The law adopted by Newton
is not accompanied with any of the experiments from which it was
deduced; and though he has given it without expressing any doubt of its
accuracy, it is, nevertheless, entirely incompatible with observation,
and has been rejected by all succeeding philosophers.
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