The logic of modern physicsBridgman, P. W. (Percy Williams)
Philosophy
The logic of modern physics
Bridgman, P. W. (Percy Williams)
Physics -- Philosophy
The most fundamental of these, which sets thermodynamics off apart from
the simpler subjects, is probably that of temperature. In origin this
concept was without question physiological, in much the same way as the
mechanical concept of force was physiological. But just as the force
concept was made more precise, so the temperature concept may be more or
less divorced from its crude significance in terms of immediate
sensation and be given a more precise meaning. This precision may be
obtained through the notion of equilibrium states. We have in the first
place the fundamental experimental fact that when a small body is placed
inside a large system, which we recognize by crude means as
comparatively invariable in temperature as time goes on, the small body
very soon acquires a steady condition, that is, it comes to equilibrium
with its surroundings. We now have the further experimental fact that if
the small body A is in equilibrium with its environment, and body B is
also in equilibrium with the same environment, there will be no change
of condition of A and B when they are brought into contact with each
other--that is, A and B are each in equilibrium with the other and also
with the environment and therefore, by definition, at the same
temperature as the environment. The temperature of the environment is
now measured in terms of some of the properties of A and B which crude
experience has shown change with the physiological temperature of A and
B. The physiological notion of temperature is thus made more precise by
being connected with the physical phenomenon of equilibrium.
Now it is at once evident that stated in this way without qualification
we have said things that are not true. It is not true in general that,
when A is in equilibrium with an environment and B is in equilibrium
with the same environment, A will be in equilibrium with B. Suppose, for
example, that the environment is a stream of water and A is a tiny water
wheel moving freely in its bearings, and that B is a similar wheel with
much friction. Then we know that B will become warm, and will not be in
equilibrium with A when brought into contact with it. Or we may choose
for A a mercury thermometer with bulb covered with putty, and for B a
similar thermometer with bulb sheathed in platinum, and we know that the
two thermometers will not register the same temperature in the water
stream. Or still more simply, we may try to read the temperature of the
air in our garden on any bright day with a silvered and with a blackened
bulb thermometer; we know that the two thermometers will read different
temperatures. It is evident, therefore, that we shall have to specify
much more carefully the conditions under which equilibrium holds if we
are to give precise significance to the temperature concept.
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