The logic of modern physicsBridgman, P. W. (Percy Williams)
Philosophy
The logic of modern physics
Bridgman, P. W. (Percy Williams)
Physics -- Philosophy
of the elastic waves and other large scale deformations of the walls.
Here again there is an arbitrary element in our procedure; if our
mechanical measuring instruments are on too gross a scale, we may miss
mechanical energy which we would catch with finer instruments.
This situation which we have just submitted to detailed analysis is, I
believe, typical of the general situation; it is not possible in the
general case to find anything which we can call heat as such. Without
further explicit examination, we can unambiguously speak of a body
losing or gaining heat only when there has been no energy interchange of
any other sort with other bodies. In such a case the heat is measured in
terms of the temperature change of the body. The heat concept is in the
general case a sort of wastebasket concept, defined negatively in terms
of the energy left over when all other forms of energy have been allowed
for.
The essential fact that a quantity of heat can by itself be defined only
in terms of a drop of temperature is somewhat obscured by the usual
method of thermodynamic analysis. In describing a Carnot engine, for
example, it is specified that the engine shall work between a source and
a sink so large that their temperature is not changed by the heat given
out or absorbed by them, so that the impression is natural that heat may
in some way be measured apart from temperature changes. This of course
is not the case; we merely require that the source and sink be so large
that their temperature changes are of a different order of magnitude
from those in the working substance itself, so that with respect to the
working substance, source and sink may be considered to be at constant
temperature.
Assuming now that we are able to measure quantity of heat in those cases
in which the concept has meaning, let us examine the first law of
thermodynamics, which we write in the form:
_dQ_ + _dW_ = _dE_
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