The Manufacture of Chocolate and other Cacao PreparationsZipperer, Paul
Science
The Manufacture of Chocolate and other Cacao Preparations
Zipperer, Paul
Cacao; Chocolate; Cocoa
It is a white, crystalline powder, so exceedingly sweet that its taste
can be perceived in a dilution of 1 in 70000. It is only slightly
soluble in cold water (1: 400) but more easily so in hot water (1: 28).
The material known as easily soluble saccharin is its sodium salt. It
contains 90 percent of saccharin and is the most easily digested
compound of saccharin.
For technical, domestic and medicinal purposes the soluble saccharin
which is only from 300-450 times as sweet as sugar is employed.
Besides being unfermentable saccharin has very slight antiseptic
properties; according to L. Nencki[139] the digestibility of albumin
is less affected by it, in the proportion usually added to articles of
food, than by Rhine wine, or by a sugar solution of equal sweetness.
Saccharin is entirely unaltered in the human organism, hence it forms
a welcome sweetening material for invalids suffering from diabetes,
corpulence or diseases of the stomach to whom ordinary sugar is
injurious. The substances known as dulcin and glucin are analogous to
saccharin in sweetening property, the first being phenetol-carbamid and
the latter a monosulphonate of amido-triazine.
The latest substance of this class is termed “sucramin” and consists of
the ammonium salt of saccharin. It is readily soluble in water, less
so in alcohol and is 700 times sweeter than sugar. It can be obtained
either in the pure form or mixed (20 percent) with sugar.
In chocolate making, saccharin is at present of little importance,
owing to the relatively small volume required as compared with sugar.
Recently it has again been recommended to the extent of 0·76 percent
as a sweetening material for cocoa powder. It would certainly be of
value in cocoa powders to be consumed by invalids and persons not
able to take sugar, although it will never come into general use. The
detection of saccharin has acquired increased importance in Germany
since the passing of the acts of October 1st 1898 and July 7th 1902,
regulating the trade in artificial sweetening materials. According to
Zipperer’s experiments, it may be detected in the following manner:
A mixture of 5 grammes of the finely powdered substance with 100 ccm
of water is allowed to stand for 2 hours, occasionally stirred and
afterwards filtered. The filtrate is acidulated with three drops of
hydrochloric acid and evaporated to 20 ccm, then shaken[140] with 50
ccm of ether in a separator and left standing for a day to separate
into two layers. The ether solution is separated and evaporated to
dryness in a beaker, the residue being mixed with 0·1 gramme of
resorcin and 4-5 drops of concentrated sulphuric acid[141] (Börnsteins
test). The mixture is then heated over a small Bunsen flame and the
melted material saturated with normal sodium hydrate. The appearance of
a strong fluorescence indicates the presence of saccharin. Saccharin
can also be easily recognised by the sweet taste of the ether residue.
II. Kinds of Starch, Flour.
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