The Manufacture of Chocolate and other Cacao PreparationsZipperer, Paul
Science
The Manufacture of Chocolate and other Cacao Preparations
Zipperer, Paul
Cacao; Chocolate; Cocoa
If as low a quantity as 5 percent of gelatine has been added to
the chocolate, as much as 10 percent of water can be added without
in any way affecting the appearance of the material, although such a
proceeding is exceedingly detrimental to the taste and durability of
the preparation. Such chocolates usually have a dull surface and, if
stored in a warm place, are apt to break up and become paler in colour;
this result can, however, be prevented by an extra addition of fat. Too
high a[163] fat content points in any case of additions of gelatine. P.
Onfroy[164] determines the addition of gelatine by boiling 5 grammes
of chocolate chips in 50 cubic centimetres of water, adding 5 cubic
centimetres of a solution containing 10 percent of lead acetate, and
then filtering the whole. If gelatine is present in the chocolate, the
liquid, on a few drops of saturated picric acid being added, leaves
a yellow, amorphous sediment. If the addition of gelatine is very
trifling, the gelatine is held in check or neutralised by the tannic
acid. The defatting is then effected by ether and the chocolate stirred
up with 100 cubic centimetres of hot water. 5-10 cubic centimetres of
a solution of lye containing 10 percent of alkali and about 10 cubic
centimetres of the above-mentioned lead acetate solution are added.
The compound of gelatine and tannic acid is soluble in the hydrate of
the alkali, and is afterwards re-deposited by the action of the lead
acetate, so that it can easily be detected by means of picric acid in
the neutralised filtrate. As picric acid is incapable of effecting the
deposition of the theobromine, the deposition observed can only be
caused by the presence of gelatine.
Like gelatine and glue, the addition of a quantity of adraganth has
the power of binding the moisture and saving the fat. A method of
estimating the quality of this vegetable gum, of which at the most 2
percent should be present, has recently been described by Welmans;
this method is explained on page ... in the microscopic section.
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