The Manufacture of Chocolate and other Cacao PreparationsZipperer, Paul
Science
The Manufacture of Chocolate and other Cacao Preparations
Zipperer, Paul
Cacao; Chocolate; Cocoa
The detection of ~foreign starch~ is possible only by use of
the microscope; by means of standard preparations an approximate
estimate may be made as to the amount and kind of meal added.[207] The
examination of starch is especially facilitated by H. Leffmann and
W. Beam’s[208] centrifugal method: the sample suspended in water is
subjected to rotation for a short time in the centrifugal apparatus.
The presence of foreign starch is shown by a white layer in the
resulting sediment. This layer can be collected and microscopically
examined for foreign starch and husk. In the case of cacao
preparations, it is always well to distinguish between unimportant
traces and quantities that justify objection.[209]
[Illustration: Fig. 102.
_A._ Silver membrane with the hairs (Mitscherlich particles) _tr_, and
the crystals _f_ and _K_.
_B._ Cocoa powder: _c_ Cotyledon tissue with cells of fat and
colouring matter, _p_ shell parenchyma, _sp_ speriods, _d_ layer of
dry cells.]
A means of detecting ~tragacanth~ in cacao preparations, has
lately been described by Welmans[210]. 5 grammes of the cacao
preparation are to be mixed with sufficient dilute sulphuric acid (1:
3) to form a thick pulp, then with 10 drops of solution of iodine (in
potassium iodide) and some glycerine. A portion of the mixture is
examined under the microscope (enlarged 160 times). The entire field
of view now appears to be thickly sown with countless blue dots, some
globular, others irregular, among which are especially to be noticed
the large tragacanth cells, resembling potato starch, which are not
seen in cocoa powder that is free from tragacanth, when similarly
prepared as an object; the small blue dots, due to cacao starch, are
visible only in the densely occupied portions.
An admixture of the ~carob~, which has been seldom observed, can
be easily recognised under the microscope by the characteristic reddish
wrinkled tubes of the fruit pulp, which are also coloured violet by
treatment with a warm solution of caustic potash.
The presence of ~earth-nut or earth-nut cake~ can be detected by
the aid of the microscope on treatment with chloral hydrate, by the
characteristic saw toothed epidermis cells of the husk of arachis seed.
~Hazelnut and walnut pulp~, so far as they are to be met with in
cacao preparations, can be distinguished under the microscope by shreds
of the tissue of the seed husks, in which broad streaks of spiral
vessels, lying close on one another, are distinctly prominent. If in
addition the woody fruit shell be admixed, it can be detected by the
great number of cells.
B. Definitions of Cacao Preparations.
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