The Manufacture of Chocolate and other Cacao PreparationsZipperer, Paul
Science
The Manufacture of Chocolate and other Cacao Preparations
Zipperer, Paul
Cacao; Chocolate; Cocoa
Cacao butter is a fairly firm fat of pleasant taste and smell, which
varies in colour between yellowish white and yellow. When freshly
expressed, it has frequently a brownish shade, passing after a short
time into a pale yellow, and turning almost white on long keeping. The
brown colour is due to pigment in suspension, which becomes sediment
in the course of melting, when the butter asumes a normal colour,
referrible to pigment dissolved in the butter oils, and secondarily
to a dissolution of the products of roasting in these liquids, rather
than to any matter in suspension. The pleasant smell and taste of cacao
butter is probably closely allied to the dissolved substances mentioned.
The fat extracted from cacao by solvents differs essentially from that
obtained by hydraulic pressure, a fact overlooked in some of even the
most recent experiments, and which therefore cannot be too strongly
emphasised. Extracted fat is yellowish white, sometimes approximating
to grey, and after having been kept a long time, the whole becomes
tinged with an actual whiteness, which first attacks the outer surface,
and then rapidly progresses towards the centre in concentric paths,
and which is a sign of rancidity. Its fracture is partly granular,
the smell is not so pronounced as that of expressed fat, being even
unpleasant at times, as in the case of faulty wares (but compare
page), and it has a keen taste. Cacao butter does not, as is generally
supposed, keep better than other vegetable fats, but is equally liable
to become rancid, as Lewkowitsch[30] demonstrates. By rancidity is
denoted that state of offensive taste and smell acquired by fatty
substances on longer or shorter keeping and especially when they are
not properly stored. What chemical re-arrangements of the respective
constituents this state presupposes is very questionable; though
it appears from the experiments of Lewkowitsch[30] and others[31]
that the formation of acids does not play as prominent a part as the
experimenter is inclined to think, nothwithstanding the marked increase
in quantity which may occur. The primary cause of rancidity will rather
be found in the oxidation products of the glycerine contained in all
fats.
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