The Manufacture of Chocolate and other Cacao PreparationsZipperer, Paul
Science
The Manufacture of Chocolate and other Cacao Preparations
Zipperer, Paul
Cacao; Chocolate; Cocoa
The specific gravity of cacao butter varies considerably, according
as it has been expressed or extracted by means of solvents. White[32]
asserts that it can only be determined when the liquefied oil has
been solidified several days. According to Rammsberger the specific
gravity of expressed butter is 0·85; that of butter extracted by
treatment with ether figures at 0·958. Hager gives the normal specific
gravity of fresh cacao butter at 15° C. as from 0·95 to 0·952; stale
butter 0·945 to 0·946, and the same figures have been confirmed by
other investigations, though Dietricht gives 0·98 to 0·981 at 100° C.
The melting point is generally regarded as 33° C.; there is in this
respect, however, a great difference between the two descriptions of
fat. Expressed fat which has been kept for some length of time melts
between 34° C. and 35° C., and these figures remain constant, so that
it is advisable to read the melting point of fat which has been in
store some time rather than that of the fresh pressed product, and take
this as a standard. All other fat shows a lower melting point.
As the melting point of freshly melted cacao butter shows considerable
fluctuation, the liquid fat must be kept in darkness and cooled with
ice for about a week, and the reading should not be taken before the
expiration of this time, as only then is it possible to obtain any
definite and final result.
Experiments on the melting point of cacao butter as carried out by
Zipperer under special conditions yielded the following values; cf.
also Table 12.
Kind of bean Melting Centigrade
point raw roasted
Machala Guayaquil 34·5 34·0
Caracas 33·5 34·0
Ariba 33·75 31·5
Port au Prince 34·25 33·8
Puerto Cabello 33·50 33·0
Surinam 34·20 34·0
Trinidad 34·00 34·0
White and Oldham[33] give the following melting points:
Guayaquil 33·6-33·9
Granada 33·0-33·3
Trinidad 31·5-32·5
Caracas 33·0-33·6
Ceylon 33·9-34·2
Filsinger and Henking found[34]:
Cauca 32·1-32·4
Bahia 32·7-33·4
Porto Plata 33·1-33·6
These results vary somewhat, but the differences are to be ascribed
to the methods employed and to the manner in which the observations
of different experimenters are carried out. Generally it may be taken
that the melting point should not be under 3° or over 35°C. The fat
solidifies between 21·5° and 23° C. (solidifying point). The fatty
acids from the fat melt at 48°-52° C.; they begin to solidify at 45°
C., the solidifying ending generally at 51°-52° C. (see table 12).
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account