The Manufacture of Chocolate and other Cacao PreparationsZipperer, Paul
Science
The Manufacture of Chocolate and other Cacao Preparations
Zipperer, Paul
Cacao; Chocolate; Cocoa
================+=========+============
| | Refractive
| Acid | index
| value | in Zeiss’s
| | butyrometer
================+=========+============
| | 46-47·8
Cacao butter |9·24-17·9| at 40° C.
| |
Oil of Almonds | — | 64-64·8
| | at 25° C.
Sesame oil | — | 67-69
| | at 25° C.
Earth-nut | |
(Arachis) oil | — | 65·8-67·5
| | at 25° C.
Hazelnut oil | — | —
| |
Cotton-seed oil | — | 67·6-69·4
| | at 25° C.
Oleo-margarine | — | 48·6
| | at 40° C.
Beef tallow | — | 49
| | at 40° C.
Wax | 19-21 | —
| |
Paraffin | — | —
| |
Stearic acid | 195-200 | —
| |
Sebin | — | —
| |
Cocoa-nut fat | — | 35·5
| | at 40° C.
The presence of cocoa-nut fat can also be shown by the etherification
of the fatty acids with alcohol and sulphuric acid, when the
characteristic odour of the ester of cocoa-nut acid occurs. Vegetable
oils, such as almond, cotton-seed, arachidic, sesame and hazelnut
oils, lower the melting point of the fatty acids and raise the iodine
value. Sesame oil is easily detected by Baudouin’s reaction, yielding
a raspberry coloration whilst pure cacao butter keeps a fine yellow
or dark brown. It is possible to detect the presence of so minute a
quantity as 1% of sesame oil, by means of Baudouin’s reaction.
The following table, containing the analytical determinations of all
fatty substances which can possibly be employed in the adulteration of
cacao butter, will serve to facilitate reference to this subject.
Public-domain text, read in full here on John Shaqi.
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