The Manufacture of Chocolate and other Cacao PreparationsZipperer, Paul
Science
The Manufacture of Chocolate and other Cacao Preparations
Zipperer, Paul
Cacao; Chocolate; Cocoa
[9] According to Schweizer (Pharmazeut. Ztg. 1898, page 389)
these substances would be represented by the chemical formula
C_{60}H_{86}O_{15}N_{4}, corresponding to 1 molecule cacao red, 6
molecules grape sugar, and 1 molecule Theobromin.
[10] Cf. Hilger, Apotheker-Ztg. 1892, p. 469.
[11] Cf. Tropenpflanzer V. 4, 1901, April-Number.
[12] Loc. cit. page 167.
[13] The leaves of the tobacco plant must also be fermented, before
they acquire their rich brown colour and peculiar aroma.
[14] Reports of the German Pharmaceutical Society 1900, Vol. 5, page
115.
[15] J. F. Hanousek, Die Nahrungs-und Genußmittel aus dem
Pflanzenreiche. p. 437.
[16] Anleitung zur mikroskopischen Untersuchung der Nahrungs-und
Genußmittel. Jena 1886.
[17] Grundriß einer Histochemie der pflanzlichen Genussmittel.
[18] See page 16 loc. cit.
[19] Cf. Dr. Stollwerck. The Cacao and Chocolate Industries.
[20] Mitscherlich, p. 57.
[21] Cacao and its Preparation; a few Experiments.
[22] Ridenour, M. American Journal of Pharmacy, 1895. Vol. 67, p. 207.
[23] Filsinger, Chemical Journal, 1887, p. 202.
[24] Z. U. N. G., 1906. Vol. 12, p. 88 et seq.
[25] The husks contain no fat when in a fresh condition but absorb fat
from the bean when the cacao is fermented and dried; especially so also
in the later process of roasting, when they become saturated with it.
[26] Klimont, Ber. d. Dtsch. chem. Ges. 34, 2636; Monatssch. f. Chem.
1902 (23) 51; 1904 (25) 929; 1905 (26) 536.
[27] Journal of the Society of Chemical Industry 1899, p. 556.
[28] Chevalier & Baudrimont, Dictionnaire des alterations.
[29] Achiv de Pharmacie 1888, Vol. 26, p. 830.
[30] See previous reference.
[31] Schmidt, Ztschr. analyt. Chem. 1898, vol. 301 p. 301; cf. also P.
Welmans, Pharm. Ztg. 1894, p. 776.
[32] Pharm. Zeitung 1898 No. 10.
[33] Cor. Assoc. Germ. Choc. Man. 1889, Vol. 5, p. 65.
[34] The Brit. and Colon. Druggist 1897 No. 21.
[35] Zeitschr. anal. Chemie.
[36] The Reichert-Meissl number (to be discussed later), according to
a communication from P. Welmans, reaches 1 Burstyn in the expressed
fat and amounts to 1·66 cc. in the extracted fat (no. of cc. of normal
potash solution to 100 grammes of fat).
[37] Dingler, Polytechnical Journal, Vol. 253, p. 281. For details of
the method compare also P. Welmans Zeitschrift für öffentl. Chemie,
1900, No. 5.
[38] Zeitschrift für anal. Chemie 1896, p. 519.
[39] Zeitschrift für öffentl. Chemie 1900, p. 95.
[40] Though Strohl Zeit. Analyt. Ch. 1896. Vol. 35. p. 166. has
obtained with a Bahia fat an iodine value of 41·7, possibly exception
due to some over-roasting of the beans or to their fat having been
extracted by a petroleum ether of very high boiling point. Cf. also
table 12.
[41] Zeitschr. Analyt. Chem. B. 21. p. 394.
[42] Correspondence of the Association of German Chocolate
Manufacturers.
[43] Zeitschrift für angew. Chem. 1898, p. 116.
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