The manufacture of earth colours : $b With thirty-one illustrationsBersch, Josef
Science
The manufacture of earth colours : $b With thirty-one illustrations
Bersch, Josef
Coloring matter; Pigments
Contrary to the old idea, it is now almost universally considered that,
instead of being of volcanic origin, graphite consists of the remains
of long-dead organisms, and in this respect is closely related to
coal. This hypothesis, however, fails to explain one point, namely the
crystalline nature of graphite; for even anthracites, which form the
oldest coals known to have had their origin in the decomposition of
organic substances, do not reveal the faintest traces of crystalline
structure. The upholders of the theory that graphite was formed by
the action of plutonic forces adduce, in support, the fact that
graphite can actually be produced, in certain chemical processes, at
high temperature. Molten cast-iron in cooling causes the separation
of carbon in the form of graphite; and the same substance is also
formed, in large quantities, in gas retorts, through the decomposition
of certain carbonaceous compounds when brought into contact with
the glowing walls of the retorts. Recent investigations, however,
have shown that the temperature necessary for the transformation of
non-crystalline carbon into crystalline graphite is by no means so
high as was formerly supposed; and it is now known that the change
takes place at as low as red heat. Possibly the two theories could be
reconciled by the assumption of a very old coal--such as is found, for
instance, as anthracite in many parts of the world--being so strongly
heated, by plutonic action, as to change into graphite.
Native graphite crystallises in the form of hexagons, mostly tabular;
but really well-developed crystals are of extremely rare occurrence,
and by far the greatest quantities of this mineral are found in the
condition of dense lumps, in which only the crystalline structure, and
not any decided crystals, can be discerned. The hardness of the mineral
fluctuates within fairly wide limits, ranging from 0·5 to 1·0. The
sp. gr. averages 1·8018–1·844, but, in the case of impure lumps may
increase to 1·9–2·2.
The following analyses will give some idea of the considerable
divergence existing between graphites from different deposits:--
SIBERIAN GRAPHITE
1 2
Carbon 94·28 40·55
Ash 5·72 56·56
Water -- 2·80
PORTUGUESE GRAPHITE
Carbon 42·69
Water (chemically combined) 3·96
Ash 53·35
BOHEMIAN GRAPHITE
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