The manufacture of earth colours : $b With thirty-one illustrationsBersch, Josef
Science
The manufacture of earth colours : $b With thirty-one illustrations
Bersch, Josef
Coloring matter; Pigments
Although levigation will remove most of the accompanying extraneous
minerals, it cannot eliminate the ash constituents of the graphite.
Experiments made in this direction have demonstrated that the ash
content of the levigated graphite is exactly the same as that of the
crude material. Whilst these ash constituents do not affect the quality
of graphite for certain of its uses, they nevertheless impair its
beautiful black colour to a considerable degree. The chemical treatment
necessary to eliminate these constituents is attended with many
difficulties, the chief of which resides in the fact that the ferric
oxide present is in a form that is not readily accessible to the action
of chemicals. For this reason, attempts to purify graphite with crude
hydrochloric acid are hardly likely to prove successful, since both
the ferric oxide and the accompanying silicates obstinately resist the
action of this acid.
In order to obtain graphite of a high state of purity, the attempt must
be made to bring this ferric oxide and the silicates into a soluble
condition. This can be accomplished in various ways, and the choice
of the method will depend on the purpose for which the graphite
is intended. For example, the operations may either be confined to
purification, or else include the attainment of a maximum condition
of subdivision. When foliaceous graphite has to be treated--and this
kind of graphite cannot, in its original condition, be used for making
lead pencils--it is preferable to employ a method which will produce
both the above results. The purification may consist in crushing the
graphite to powder, and fusing this with a mixture of sulphur and
carbonate of soda, whereby the silicates present are converted into
soluble compounds, and the ferric oxide into ferric sulphide. On
extracting the melt with water, a portion of the contained salts pass
into solution and is carried off. The residue is then treated with
dilute hydrochloric acid, which dissolves out the ferric sulphide, with
liberation of sulphuretted hydrogen, and leaves the graphite in a very
pure condition after washing.
In order to render foliaceous graphite suitable for lead pencils, a
different method is pursued, but should only be employed in special
circumstances, on account of the expense entailed.
According to the process recommended by Brodie, the graphite, ground to
coarse powder, is mixed with about one-fourteenth of its own weight of
chlorate of potash, this mixture being heated, with two parts by weight
of sulphuric to each part of graphite, in a water bath so long as fumes
of hypochlorous acid continue to be disengaged. The heating must be
performed in stoneware or porcelain vessels, those made of any other
materials being strongly corroded by the chlorine compounds formed.
Public-domain text, read in full here on John Shaqi.
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