The manufacture of earth colours : $b With thirty-one illustrationsBersch, Josef
Science
The manufacture of earth colours : $b With thirty-one illustrations
Bersch, Josef
Coloring matter; Pigments
This great divergence in the physical character of clays is due to
their method of formation. Clay originated in the weathering of
felspar, which chiefly consists of a double salt, a compound of the
silicates of alumina and potash. Under the influence of air and water,
this compound is decomposed, the potassium silicate passing into
solution, whilst the aluminium silicate, being insoluble in water, is
carried away by that medium. When the water can no longer carry the
particles of aluminium silicate in suspension--for example when it
reaches a sea or lake--the silicate settles down to the bottom, and a
deposit of clay is formed.
If the original felspar was very pure, and in particular very low
in iron, the resulting clay will be of a handsome white colour. An
example of this is afforded by kaolin, or porcelain earth, which is
preferably used for making china. If, however, the felspar contained a
considerable proportion of ferric oxide, the resulting clay is yellow;
and if stones or mussel shells became incorporated with the clay prior
to deposition, these bodies will be found as inclusions in the deposit,
and such clay will require much troublesome preparation--grinding and
levigation--before it is fit for use.
For the purposes of the colour-maker, the most suitable clay is one
that is pure white, free from inclusions, and does not change colour
when exposed, in a finely divided state, to the action of the air.
Many clays that were originally white gradually assume a yellow tinge
on prolonged exposure to air and moisture, because the clay contained
ferrous oxide, which changes, in the air, to the stronger pigment,
ferric oxide.
Many kinds of clay merely require a simple levigation to fit them for
use as pigment. The lumps of freshly dug clay are placed in large
tanks, etc., filled with water and stirred up continuously in order
that, instead of forming a plastic mass which is very difficult to
distribute in water, the particles detached from the lumps may pass at
once into suspension. This turbid water is then transferred to another
tank, etc., where the minute particles of clay are allowed to settle
down, and the water becomes quite clear.
Where this work is carried on on a large scale, it is advisable to put
the freshly won clay into large pits close to the clay deposit, and
to leave it there, covered with water, during the winter season. The
freezing of the water breaks down the larger lumps of clay, by the
resulting expansion, and this facilitates the subsequent levigation,
the cohesion between the particles being destroyed.
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