The manufacture of earth colours : $b With thirty-one illustrationsBersch, Josef
Science
The manufacture of earth colours : $b With thirty-one illustrations
Bersch, Josef
Coloring matter; Pigments
This behaviour is apparently due to the presence of the lime, the
explanation being that the fatty acids always present in the oils and
varnishes used for the paint combine with the lime to form compounds
which, from the standpoint of the chemist, must be regarded as soaps.
The small lumps already mentioned really consist of lime soap, and
the formation of these colourless compounds accounts for the lessened
covering power.
Given a fine white clay, otherwise capable of forming a valuable
pigment, it is sometimes possible, by simple means, to eliminate
accompanying lime, provided the amount of the latter is not too great,
and also provided that very cheap hydrochloric or acetic acid is
available. The acid need not be pure, and the impure but very strong
pyroligneous acid, which is very cheap on account of its empyreumatic
smell, may be used.
To eliminate lime from the clay, the still moist levigated mass is
introduced, in small quantities, into a vat containing the requisite
quantity (see later) of hydrochloric or acetic acid, the addition being
continued until the liquid gives only a faintly acid reaction with
blue litmus paper. When the clay is run in, effervescence is produced
by the liberation of the carbon dioxide displaced by the stronger acid
employed.
The amount of lime present in a clay may be determined by very simple
means. A small sample of the clay is dried by artificial heat, until
of constant weight, and exactly 100 parts by weight of the dry mass
are placed in a glass and suffused with hydrochloric acid, sufficient
of the latter being used to make the liquid still strongly acid after
effervescence has ceased.
The contents of the glass are transferred to a filter, and washed
with pure water so long as the washings continue to redden blue
litmus paper. The residue is then dried until of constant weight, and
the difference between the initial and final weights will give the
percentage of substances soluble in hydrochloric acid.
After performing this simple test on a clay, it is easy to calculate
the quantity of acid needed to extract all the soluble constituents
from a given weight of the material. All that is necessary is to
measure the volume of acid required to extract a small quantity of
the clay completely. Thus, if one pint of the acid at disposal is
sufficient to treat one pound of the clay, the amount needed for a
given quantity of clay is a simple matter of calculation.
Since, on account of the cost of pure hydrochloric acid, crude acid
will always be used, it will be necessary to remember that this crude
acid always contains ferric oxide in solution--this being the cause of
its yellow colour. If the amount of acid taken is barely sufficient to
combine the whole of the lime, leaving the latter slightly in excess,
the ferric oxide--which would otherwise tinge the clay yellow--will be
precipitated.
Public-domain text, read in full here on John Shaqi.
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