The manufacture of earth colours : $b With thirty-one illustrationsBersch, Josef
Science
The manufacture of earth colours : $b With thirty-one illustrations
Bersch, Josef
Coloring matter; Pigments
The solution will always be cloudy, owing to the partial precipitation
of the hydroxide by the lime in the water; but this is immaterial.
For the precipitation, a milk of lime is prepared by slaking one to
two parts of quicklime (according to the quantity of ferrous sulphate
to be treated) in water, and stirring this up in enough water to make
a thin milk. Care must be taken to exclude any large particles of
lime, since these would find their way into the finished product and
make the colour uneven. On this account, the milk of lime should be
carefully strained through a loosely woven cloth or fine sieve, into
the precipitation vessel.
The ferrous sulphate solution is then poured in, the mixture being kept
stirred, and an ugly, grey-green precipitate is produced, consisting of
a mixture of ferrous hydroxide and calcium sulphate, the reaction being
explained by the equation:--
FeSO{4} + Ca(OH){2} = Fe(OH){2} + CaSO{4}.
The larger the amount of ferrous sulphate solution added to the milk
of lime, the darker the resulting ochre. As soon as all the ferrous
sulphate is in, the stirring is suspended, and the liquid is left until
quite clear. The water is drawn off through tapholes in the side of
the vessel, care being taken not to disturb the fine precipitate, and
fresh water is added, in which the deposit is stirred up and again left
to settle down. This operation, which is once or twice repeated, is to
wash the precipitate.
When this object has been sufficiently accomplished, the mass is
shovelled out of the vessel and spread thinly on boards, where it is
left until the desired shade of colour has been attained, the colour
changing quickly on exposure to air, owing to the oxidation of the
ferrous hydroxide into ferric hydroxide. To ascertain whether oxidation
is complete, a large lump of the mass is broken across; and if it is
of a uniform yellow-brown colour throughout, without being darker on
the outside than in the middle, all the ferrous hydroxide will have
been transformed into the ferric state. The product can now be dried at
once, and when ground will be ready for sale.
To obtain different varieties from the product, it is carefully heated
(in a finely powdered condition) in shallow pans; but the operation
needs caution, or the water in the gypsum present will be expelled,
giving rise to drawbacks that are manifested when the colour is used.
For instance, in mixing such a colour with water, the gypsum would
again absorb water and cause the whole mass to set as a useless
solid lump. Since gypsum parts with its water at a comparatively low
temperature, it is better not to heat these cheap ochres at all, but
to obtain the various shades by modifying the proportion of ferrous
sulphate employed.
Public-domain text, read in full here on John Shaqi.
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