The manufacture of earth colours : $b With thirty-one illustrationsBersch, Josef
Science
The manufacture of earth colours : $b With thirty-one illustrations
Bersch, Josef
Coloring matter; Pigments
The foregoing are only a few examples of brown or red-brown earth
colours. In all these minerals the pigmentary principle is iron, in
combination either with oxygen alone (ferric oxide), with oxygen and
water (ferric hydroxide), or silica compounds (ferric silicate), and
always associated with certain quantities of other metallic oxides,
especially alumina and manganese oxide. Although but few of these
minerals have gained any special reputation as pigments, there is
no doubt that similar minerals, which are certain to occur in or
near many deposits of iron ores, could equally well be used for that
purpose. There is no need to emphasise that the discovery of such a
mineral would be a very valuable find, and that the products obtainable
therefrom could be utilised to great advantage.
The testing of a mineral for its suitability as pigment is a very
simple matter, all that is required being to subject a small quantity
to the same treatment that is applied to the earth colours on a large
scale. For this purpose a few pounds of the mineral are levigated, and
the residue is dried. To ascertain the tones obtainable by calcination,
small samples--of about 100 grms.--are placed in crucibles, and
gradually heated in a furnace. When the masses have attained a
sufficient temperature, the samples are taken out of the furnace,
at intervals of ten minutes, and left to cool. It will then not be
difficult to decide whether the mineral is at all suitable for the
purposes of the colour-maker; and if so, these tests afford at once an
indication of the temperature and time the mineral must be heated in
order to obtain pigments of definite tones.
COLOGNE EARTH (COLOGNE UMBER)
The application of the term “umber” to this earth can only have been
based on a certain similarity in colour to true umber. In chemical
composition, however, the two are quite different, Cologne earth really
consisting of a mixture of humic substances. It is well known that the
rotted wood found in the interior of decaying trees is often a handsome
brown colour; and all woody matter, after lying a very long time,
finally acquires this colour, owing to the transformation of the wood
into dark-coloured compounds richer in carbon. This effect can be seen
on the large scale, in Nature, in the case of coal, brown coal and peat.
Now Cologne earth consists of a brown-coal mould, dark brown in colour,
of earthy character and of such low cohesive power that it crumbles
with ease. Owing to this character, Cologne earth can be easily ignited
by the flame of a candle, and then burns with a strong, smoky flame,
leaving very little ash and disseminating the peculiar bituminous smell
given off when brown coal is burned.
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