The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
A noteworthy process is due to Liebig. Saltpetre is melted in a
crucible, and heated to a temperature below that at which oxygen is
evolved. Dry chrome yellow is introduced so long as effervescence
occurs; the fused mass appears, whilst liquid, deep black. As soon as
it is in quiet fusion it is poured on a cold plate. In consequence of
the rapid cooling it becomes brittle and can be easily powdered. The
hot mass is broken up and boiled with water, potassium chromate going
into solution. The chrome red made by this process is little inferior
in brilliance to vermilion.
According to Prinveault a handsome chrome red is obtained by treating
25 grammes of neutral lead carbonate with 10 grammes of yellow
potassium chromate dissolved in 5 litres of water, boiling for half
an hour, washing the violet precipitate, and finally treating with 1
gramme of sulphuric acid diluted with 100 grammes of water.
=Cobalt Red= consists of cobalt phosphate. It was first recommended
by Salvetat. It is obtained by precipitating a solution of a cobalt
salt by sodium phosphate. After drying at the ordinary temperature the
precipitate has a beautiful rose-red colour. By careful heating, the
shade becomes more violet according to the temperature used.
=Cobalt-Magnesia Red.=—When magnesia is moistened with the solution
of a cobalt salt and strongly heated, a rose-red mass is obtained
which can be used as an extremely durable artists’ colour. It probably
consists of a compound of cobalt oxide with magnesia. The method of
preparation is as follows: Magnesium carbonate is mixed to a thin paste
with a dilute solution of cobalt nitrate; this is heated and stirred
until quite dry, when the residue is strongly heated in a covered
crucible. In the manufacture of this and other cobalt pigments it is of
particular importance to prevent the entry of the fire gases into the
crucible. Unless this is done a product of good colour is not obtained.
=Cobalt Arsenate.=—By precipitating a cobalt salt with sodium arsenate,
a violet-red precipitate is obtained which leaves a fine durable red on
heating. The mineral erythrite has a similar composition and colour.
This pigment has a bright shade, is permanent, and although it contains
arsenic is not particularly poisonous, since after fusion it is little
soluble.
=Chromium Stannate.=—This artists’ pigment, which may be used in oil
and porcelain painting, is made in the following manner (Gentele): 1
kilogramme of tin is converted by strong nitric acid into metastannic
acid, 50 grammes of potassium chromate are dissolved in 1 litre of
water, the solution mixed with 2 kilogrammes of chalk and 1 kilogramme
of powdered quartz, and finally with the metastannic acid. The mixture
is dried and strongly heated. The temperature must be raised to a white
heat, at which the mass sinters and acquires a dark rose-red colour. It
is then completely extracted with boiling water, when a fine powder is
left.
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