The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
According to the directions of Fuchs, a fine purple is obtained by
mixing a solution of stannous chloride with sufficient ferric chloride
solution to give the mixture a green colour. Part of the ferric salt is
then reduced to ferrous salt, whilst the stannous chloride is partially
oxidised. At the same time a solution of gold chloride is made; this
must be quite free from nitric acid and contain 1 part of the salt in
400 to 500 parts of water. The tin solution is added drop by drop to
the gold solution with constant stirring; the mixture becomes turbid,
but the precipitate requires a long time to settle on account of its
fine state of division. The depth of colour shown by the purple varies
according to the strength of the solutions.
M. Müller states that the following process gives the best results: The
quantity of stannic chloride equivalent to 9 grammes of stannic acid
is dissolved in 200 cubic centimetres of water; potassium carbonate
is added to alkaline reaction, then 1 gramme of gold in the form of
chloride. Grape sugar is added to the mixture, which is made up to 300
cubic centimetres by water, and warmed until the brightest shade is
reached. When a very gelatinous mass is formed after the addition of
the potassium carbonate it is heated for a short time before adding the
gold solution and grape sugar.
Wächter gives directions for obtaining pale and deep shades. To obtain
the pale purple 5 grammes of tin are dissolved in _aqua regia_, the
solution evaporated to dryness on the water bath, the solid residue
mixed with a solution of 2 grammes of stannous chloride and dissolved
in 10 litres of water. To this liquid is added a solution of 0·5
gramme of gold in _aqua regia_, and immediately 50 grammes of ammonia
to neutralise free acid. The precipitate separates spontaneously from
the dark red liquid; its formation may be hastened by adding sulphuric
acid. The washed precipitate is mixed whilst moist by means of a
silver spatula with 20 grammes of lead flux, 2 grammes of red lead, 1
gramme of quartz sand, and 1 gramme of calcined borax. The mixture is
then dried; it produces a purple red colour. If 3 grammes of silver
carbonate are added, a clean, pale purple pigment results.
The deep purple is made by mixing a solution of 0·5 gramme of gold
in 10 litres of water with 7·5 grammes of stannous chloride solution
(specific gravity, 1·7) whilst stirring, and adding a few drops of
sulphuric acid. The washed precipitate is mixed with 10 grammes of lead
flux and 0·5 gramme of silver carbonate.
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