The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
If ores are employed which contain only a small quantity of cobalt, the
same quantity of glass is melted time after time with fresh quantities
of the poor ore. At each operation cobalt is taken up. In place of
glass a mixture of potash and very fine quartz sand may be used with
advantage. It produces that species of glass which most easily takes
up cobalt oxide. The quartz sand is generally made by igniting flint
and quenching in water to facilitate the grinding; it is then powdered.
River sand is generally so impure that it would produce a brown or
green coloured glass, which, when fused with cobalt ores, would give
smalts of a bad shade.
=2. Fusion of the Charge.=—This process is very similar to the fusion
of ordinary glass. The materials, in very fine powder, are carefully
mixed and then ”fritted,” that is, heated until the mass sinters
together without melting. The real fusion is accomplished in glass
furnaces. The fritted mass is fused in small ”glass pots” made of
fire-clay, in a furnace similar in principle to the ordinary glass
furnace. The glass pots are made rather small, to hold about 50
kilogrammes, in order to obtain as homogeneous a product as possible.
They are placed to the number of six in a furnace heated by coal, in
which a very high temperature can be obtained. This is essential,
because the charge has a high melting point and must be made quite
fluid in order that impurities may settle.
The furnace must be slowly heated at first to prevent the pots from
cracking. When they are once heated the temperature is raised to
fuse the charge, which is repeatedly stirred so that the residues
may sink to the bottom. These residues consist chiefly of metallic
sulphides and arsenides. After six to seven hours’ fusion the stirring
is discontinued, and the temperature raised for a short time to the
highest it is possible to attain, so that the smalts may be as fluid
as possible. When this is the case it can be drawn out into long thin
threads. The melted glass is then taken out and poured into cold
water. The rapid cooling makes it extremely brittle, and considerably
facilitates the powdering.
When new pots are used for the fusion, their walls are considerably
attacked by the alkalis contained in the glass. In order to prevent
this a small quantity of common smalts is fused in them before the
introduction of the real charge; the inner surface then becomes covered
with a protective glaze.
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