The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
According to A. Casali, a chrome green which satisfies every
requirement is obtained by strongly igniting 1 part of potassium
bichromate with 3 parts of burnt gypsum. After ignition the mass is
boiled with very dilute hydrochloric acid. In this process the chromic
oxide is produced according to the following equation:—
2K₂C₂O₇ + CaSO₄ = 2Cr₂O₃ + 2K₂SO₄ + 2CaO + 3O₂.
On boiling with hydrochloric acid the lime is dissolved; when the
liquid remains distinctly acid after long boiling it is poured off and
the chromium oxide washed with hot water and dried.
In another method ammonium chromate is very gradually heated. At a
certain temperature the salt suddenly becomes incandescent and is
converted into a dark green, almost black, mass which has a very
similar appearance to dry tea-leaves. The green obtained after
washing and powdering is handsomer the lower the temperature of the
decomposition.
Chromium oxide may also be made in the wet way, but the product does
not compare in beauty with that obtained in the dry way. When soda
solution is added to a solution of chrome alum, a greyish green
precipitate of chromium hydroxide is formed; on ignition of the washed
precipitate pure chromium oxide remains.
In a similar manner chromium oxide is produced by precipitating with
soda solution the solution of chromium chloride obtained by adding
hydrochloric acid to a solution of potassium bichromate, and then
alcohol in small quantities, so long as a reaction occurs and the green
liquid becomes deeper in colour.
A handsome and bright chrome green is only obtained when the potassium
bichromate is quite free from iron, a very small quantity of which has
a very harmful effect upon the brightness of the pigment. The author
has found that there is no great difficulty in rendering commercial
potassium bichromate tolerably free from iron by recrystallisation. As
much of the salt is dissolved in boiling water as it will take up, the
boiling solution is quickly filtered and rapidly cooled with continual
stirring; the fine crystalline meal is left on a strainer until no more
liquid filters through, and then washed with a little cold water to
remove the mother liquor. The salt obtained by this simple operation is
of great purity and always produces chrome green of a good shade.
Public-domain text, read in full here on John Shaqi.
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