The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
=Emerald Green.=—This pigment must not be confounded with the more
important copper compound previously described, to which the name
emerald green is usually applied. It consists of chromium hydroxide
obtained by precipitating a solution of the green modification of a
chromium salt by zinc hydroxide. After careful washing it has a dull
green shade; it is a very durable pigment.
=Chrome Green Lake= is a mixture of chromium oxide with alumina; it
is obtained by precipitating a solution of alum and a chromium salt
by a soda solution. The precipitate, which contains aluminium and
chromium hydroxides, on ignition takes a paler shade in proportion to
the quantity of alumina it contains. For the chromium salt a solution
of potassium bichromate, which has been allowed to stand with sulphuric
acid and alcohol until if has acquired a pure green colour, may be used.
=Turkish Green.=—This pigment, which retains its fine green colour in
artificial light, is prepared in a peculiar manner: 40 parts of alumina
free from iron, 30 parts of cobalt carbonate and 20 parts of chromium
oxide are thoroughly ground in a mortar. The mixture is placed in a
porcelain tube, which is exposed to a strong white heat whilst pure
oxygen is led through. The oxygen may be replaced by air if it is
previously heated and under pressure.
Another recipe for Turkish green is to intimately mix 4 parts of
freshly precipitated alumina with 3 parts of cobalt carbonate and
2 parts of chromium oxide, heat the mixture in a crucible at a
white heat, powder and levigate. Turkish green has a characteristic
bluish-green colour; the shade is inclined to blue or green by
increasing the quantity of cobalt carbonate or chromium oxide.
=Leaf Green= is a pale green, very durable pigment similar to chrome
green lake. It is obtained by igniting mixtures of chromium oxide with
pure aluminium hydrate; the paleness of the shade is in proportion to
the amount of alumina.
=Chromium Phosphate Pigments.=—Several chromium phosphates are used as
pigments; the more important are described here.
=Arnaudan’s Green= is chromium metaphosphate; it is obtained by
intimately mixing 128 parts of neutral ammonium phosphate with 149
parts of potassium bichromate by long grinding, and carefully heating
the mixture at 170° to 180° C., but not higher, until the mass is pure
green. It is then brought into hot water and thoroughly washed; it has
a very handsome green colour, which is not altered in artificial light.
Ammonium arsenate may be used in the place of ammonium phosphate; a
handsomer green is then obtained, which is, however, very poisonous.
Public-domain text, read in full here on John Shaqi.
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