The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
The mixing is generally accomplished by mechanical arrangements. If
dry colours are to be mixed, rotating cylinders may be used; these are
filled with the materials to be mixed, well closed and rotated about
the axis as long as may be necessary. It should be observed that when
colours which have a very different specific gravity, such as chrome
yellow and Prussian blue, are to be mixed, the cylinders must be
rotated for a much longer time than when colours of approximately equal
specific gravity are to be united.
In working in the wet way, which is to be preferred, sufficient water
is added to the colours to make a paste thin enough to be mixed by
spatulas; the mixture is thoroughly stirred and the pulp ground in
ordinary mills until the mixture is quite uniform. Already whilst on
the mills the pulp becomes thicker in consequence of evaporation; when
the grinding is finished it is spread out in thin layers so that it may
dry as quickly as possible. This is important in the case of mixtures
whose constituents have very different specific gravities, otherwise
the heavier pigment may sink to the bottom of the paste and the mass
thus lose its uniformity.
The compound green pigments come into the market under most varied
names, which are often entirely without connection with their chemical
composition. Such names are: mineral green, English green, oil green,
green vermilion; the most common are chrome green and Brunswick green.
It should be noted that these names are more strictly applied to simple
colours previously described.
=Chrome Green= is generally made by mixing deep chrome yellow and
Prussian blue; it can naturally be obtained in all possible shades.
The brightness of this already handsome pigment can be considerably
increased by the addition of a small quantity of indigo carmine. In
this case the mixing is best done by adding a solution of the indigo
carmine to the stiff paste and again sending the mixture through the
mill.
By additions of white substances paler shades of chrome green are
obtained; levigated terra alba or white pipe clay can be advantageously
employed.
=Elsner’s Chrome Green= is obtained by preparing a solution of yellow
prussiate of potash and potassium chromate and another solution of lead
acetate and ferric chloride. The two liquids are mixed with vigorous
stirring; according to the proportions of the materials a blue or a
yellow shade of green is produced.
=Silk Green.=—Forty-one parts of lead nitrate are dissolved in 20 to 30
times the weight of water, the solution is boiled in a copper pan, and,
according to the shade required, 10 to 30 parts of fine Chinese blue
are added. After well stirring, a solution of 10 parts of potassium
bichromate and 1 part of nitric acid is poured into the boiling liquid,
the mixture is again well stirred, the precipitate allowed to settle,
washed and dried. The green pigment obtained in this way has a peculiar
silky lustre, hence the name ”silk green”.
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